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The Role of Eh in Nuclear Waste Form Dissolution

Published online by Cambridge University Press:  25 February 2011

W. Phelps Freeborn  and
William B. White
W. Phelps Freeborn
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
William B. White
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
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Abstract

A series of experiments was conducted to evaluate the significance of redox potential, Eh, as an independent opensystem variable in the dissolution of nuclear waste glasses and ceramics. The standard platinum electrode can be used in leach solutions. Measurements on couples with rapid kinetics such as Fe+++/Fe++ give results in agreement with thermodynamic calculations. Highly reducing leaching solutions can be obtained by passing hydrogen through the solvent in the presence of a palladium catalyst.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 26: Symposium D – Scientific Basis for Nuclear Waste Management VII , 1983 , 719
Copyright
Copyright © Materials Research Society 1984

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References

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