Hostname: page-component-78c5997874-ndw9j Total loading time: 0 Render date: 2024-11-09T14:09:24.424Z Has data issue: false hasContentIssue false

A Review of 25 years of Corrosion Studies on HLW Container Materials at the CEA

Published online by Cambridge University Press:  19 October 2011

Max Helie*
Affiliation:
[email protected], French Atomic Energy Commission, Physico Chemistry, DPC/SCCME, Bât 458, Centre d'Etudes de Saclay, Gif sur Yvette, 91191, France, 0 11 33 1 6908 2016, 0 11 33 1 6908 1586
Get access

Abstract

The Commissariat à l'Énergie Atomique (CEA, French Atomic Energy Commission) has been involved in researches on nuclear waste management for more than 25 years. One of the key issues is the prediction of the long term behavior and aging of the High Level Waste (HLW) containers in order to develop concepts that will ensure the confinement of the activity over extremely long periods of time.

Preliminary studies were carried out on two concepts, one of a thin "corrosion resistant" container made of titanium or nickel base alloy, and the other on a thick "corrosion allowance" container made or carbon steel.

The results of these experiments showed that the "corrosion resistant" concept led to a high uncertainty on the development and propagation rate of localized forms of corrosion, and the concept of geological disposal in an argillaceous host formation of thick waste containers made of carbon steel was chosen as the reference. Studies are still in progress to better assess the corrosion mechanisms relevant to this situation in order to provide reliable models for the long term prediction of the containers corrosion behavior.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Plante, G., HÉLIE, M., “Corrosion Behaviour of Container Materials for Geological Disposal of High Level Waste,” Commission of the European Communities, Nuclear Science and Technology, EUR 10398 (1986).Google Scholar
2. HÉLIE, M., Plante, G.,' “HLW Container Corrosion in Geological Disposal Conditions,” Proceedings of Scientific Basis for Nuclear Waste Management IX, MRS, pp. 445452, Stockholm, Sweden, September 9–11 1985.Google Scholar
3. HÉLIE, M., DESGRANGES, CL., PERRIN, ST., “Prediction of Corrosion Behavior of HLW Containers in the Framework of the French Interim Storage Concept,” Nuclear Technology, Vol.155, pp.120132, August 2006.Google Scholar
4. MACDONALD, D., “Passivity - the key to our metal-based civilization,” Pure Applied Chemistry Vol.71, pp. 951978, 1999.Google Scholar