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Retardation Effects in the Hydration of Cement-Fly Ash Pastes

Published online by Cambridge University Press:  25 February 2011

Michael W. Grutzeck
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
Wei Fajun
Affiliation:
Permanent Address–Wuhan Institute of Building Materials, Hubei, China
Della M. Roy
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
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Abstract

The hydration of high-calcium and low-calcium fly ash-cementmixtures was investigated to determine the effect of fly ash upon the hydration of a Type I portland cement, and to determine the associated mechanisms of hydration. When blended with portland cement, both fly ashes retarded the early hydration process, the high-Ca more so than the low-Ca. Analyses of solution compositions and calorimetric (heat of hydration) measurements were made. The retardation and hydration effects are discussed in terms of solution composition data and solid phase characterization. The hydration effects were interpreted and compared with the results of previous work.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

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References

1. Fajun, Wei, Grutzeck, M.W. and Roy, D.M., Cem. Concr. Res. 15, 174 (1985).10.1016/0008-8846(85)90024-9Google Scholar
2. Ogawa, K., Uchikawa, H. and Takemoto, K., Cem. Concr. Res. 10, 863 (1980).10.1016/0008-8846(80)90032-0Google Scholar
3. Kawada, N. and Nemoto, A., Sement Gijutsu Nempo. 22, 124 (1968).Google Scholar
4. Jawed, I. and Skalny, J., Effects of Fly Ash Incorporation in Cement and Concrete, Ed. Diamond, S., p. 60, Proc. M.R.S. Meeting, Boston, MA (1981).Google Scholar
5. Cabrera, J.G. and Plowman, C., Proc. 7th Int. Cong. Chem. Cem. 3, IV-85 Paris (1980).Google Scholar
6. Plowman, C. and Cabrera, J.G., Cem. Concr. Res. 14, 238 (1984).10.1016/0008-8846(84)90110-8Google Scholar
7. He, Jun-Yuan, Scheetz, B.E. and Roy, D.M., Cem. Concr. Res. 14, 505 (1984).Google Scholar
8. Jones, F.E., J. Phys. Chem. 49, 344 (1945).10.1021/j150442a007Google Scholar
9. Wu, Zhao-Qi and Young, J.F., J. Am. Ceram. Soc. 67 (1), 48 (1984).10.1111/j.1151-2916.1984.tb19146.xCrossRefGoogle Scholar
10. Idorn, G.M. and Henriksen, K.R., Cem. Concr. Res. 14, 463 (1984).10.1016/0008-8846(84)90120-0Google Scholar
11. Diamond, S., Effects of Fly Ash Incorporation in Cement and Concrete, Ed. Diamond, S., p. 12, Proc. M.R.S. Meeting, Boston, MA (1981).Google Scholar
12. Malek, R.I.A. and Roy, D.M., Proc. 6th Intl. Conf. on Alkalis in Concretes, Research and Practice, Idorn, G.M., Rostam, Steen, Eds., p. 223, Danish Concrete Association, Copenhagen (1983).Google Scholar
13. Bakker, W.T., Ed., Workshop Proceedings: Research and Development Needs for the Use of Fly Ash in Cement and Concretes, EPRI CS-2616-SR, pp. 2–1 and 5-1, Electric Power Research Institute, Palo Alto, CA (1982).Google Scholar
14. Roy, D.M. and Idorn, G.M., ACI Journal 7943, 444 (1982).Google Scholar