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Resonant Raman Characterization of Polyparaphenylene Based Carbon Materials

Published online by Cambridge University Press:  10 February 2011

A. Marucci ,
S. D. M. Brown ,
M. A. Pimenta ,
M. J. Matthews ,
M. S. Dresselhaus  and
M. Endo
A. Marucci
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
S. D. M. Brown
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
M. A. Pimenta
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
M. J. Matthews
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
M. S. Dresselhaus
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139 Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, MA 02139
M. Endo
Affiliation:
Faculty of Engineering, Shinshu University, Nagano, 380, Japan
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Abstract

The structure of the polymer polyparaphenylene (PPP), heat-treated at temperatures (THT) between 650°C≤ THT ≤750°C and prepared according to either the Kovacic or the Yamamoto methods, is studied by the resonant Raman technique using five laser excitation energies Elaer in the range 1.92–3.05 eV. The resonant Raman analysis allows identification of the benzenoid and quinoid forms of PPP as well as the amorphous material associated with the onset of the carbonization process. The results enable us to follow the evolution of the PPP polymer with heat-treatment temperature and to determine the differences between the materials prepared using the two different methods.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 15
Copyright
Copyright © Materials Research Society 1999

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References

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