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Recombination of Localized Excitons in InGaN Single- and Multiquantum-Well Structures

Published online by Cambridge University Press:  10 February 2011

S. Chichibu
Affiliation:
Faculty of Science and Technology, Science University of Tokyo, 2641 Yamazaki, Noda, Chiba 278, addr-lineJapan
T. Azuhata
Affiliation:
Department of Electrical, Electronics, and Computer Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169, Japan
T. Sota
Affiliation:
Department of Electrical, Electronics, and Computer Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169, Japan
S. Nakamura
Affiliation:
Department of Research and Development, Nichia Chemical Industries Ltd., 491 Oka, Kaminaka, Anan, Tokushima 774, Japan
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Abstract

Spontaneous emission mechanisms of InGaN single quantum well (SQW) blue and green light emitting diodes (LEDs) and multiquantum well (MQW) laser diode (LD) structures were investigated. Their static electroluminescence (EL) peak was assigned to the recombination of excitons localized at certain potential minima in the quantum well (QW). The transmission electron micrographs (TEM) indicated fluctuation of In molar fraction in the QWs. The blueshift of the EL peak caused by the increase of the driving current was explained by combined effects of the quantum-confinement Stark effect and band filling of the localized states by excitons.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1.For a review see, for example, Strite, S. and Morkoc, H., J Vac. Sci. Technol. B10, 1237 (1992)Google Scholar
2. Nakamura, S., Senoh, M., Iwasa, N., Nagahama, S., Yamada, T. and Mukai, T., Jpn. J. Appl. Phys. 34, L1332 (1995).Google Scholar
3. Nakamura, S., Senoh, M., Nagahama, S., Iwasa, N., Yamada, T., Matsushita, T., Kiyoku, H and Sugimoto, Y, Jpn. J. Appl Phys 35, L74 (1996), Jpn. J. Appl. Phys. 35, L217 (1996), Appl Phys. Lett 68, 3269 (1996).Google Scholar
4. Akasaki, I, Sota, S, Sakai, H., Tanaka, T., Koike, M and Amano, H, Electron. Lett. 32, 1105 (1996)Google Scholar
5. Itaya, K et al., Jpn. J. Appl. Phys. 35, L1315 (1996)Google Scholar
6. Nakamura, S., Senoh, M., Nagahama, S., Iwasa, N, Yamada, T., Matsushita, T., Sugimoto, Y. and Kiyoku, H., IEEE Lasers and Electro-Optics Society Meeting (LEOS’96), PD 1.1, Nov 20, 1996.Google Scholar
7. Chichibu, S, Azuhata, T., Sota, T. and Nakamura, S., J. Appl. Phys. 79, 2784 (1996), Proceedings of the International Symposium on Blue Laser and Light Emitting Diodes (Ohmsha, Tokyo, 1996), pp.202, S Chichibu, H. Okumura, S Nakamura, G Feuillet, T Azuhata, T Sota and S Yoshida, to be published in Mar. 15 issue of Jpn. J. Appl. Phys. 36B (1997).Google Scholar
8. Nakamura, S., Jpn. J. Appl. Phys. 30, L1705 (1991)Google Scholar
9. Aspnes, D. E., Surf Sci. 37, 418 (1973).Google Scholar
10. Chichibu, S., Shikanai, A., Azuhata, T., Sota, T., Kuramata, A., Horino, K., and Nakamura, S., Appl. Phys. Lett. 68, 3766 (1996), A. Shikanai, T. Azuhata, T. Sota, S. Chichibu, A. Kuramata, K Horino, and S. Nakamura, [to be published in Jan. 1st issue of J. Appl. Phys (1997)].Google Scholar
11. Tsutsui, H, Igarashi, T., Azuhata, T, Sota, T., Chichibu, S., and Nakamura, S., (submitted to Phys Rev B; unpublished). The Eex value in GaN/Al0.1Ga0.9N QW was calculated by the variational method according to G Bastard, E. E. Mendez, L. L. Chang, and L Esaki [Phys Rev. B 26, 1974 (1982)] In the calculation, we started from the Hamiltonian suitable to QWs including mass and dielectric constant anisotropy, assuming an infinite barrier height to simplify the calculation. After variable transformations for Z coordinates (perpendicular to the QW plane) which formally remove the mass anisotropy in the Hamiltonian, Eex was calculated using the trial function for the excitonic relative motion given by exp{-[ρ2+( Ze-Zh)2]1/2/λ }, considering the fact that the 3D exciton Bohr radius is as small as 3 4 nm Here λ is the variational parameter, ρ is the absolute value of the relative position of electron and hole in the QW plane, and Ze(Zh) is the transformed Z coordinate of the electron (hole).Google Scholar
12. Harris, C. I, Monemar, B., Amano, H., and Akasaki, I., Appl. Phys. Lett. 67, 840 (1995).Google Scholar
13. Amano, H. and Akasaki, I., Extended Abstracts of Int.Conf. Solid State Mater. & Dev. (1995)Google Scholar
14 Kisielowski, C. and Liliental-Weber, Z. (private communication 1996)Google Scholar
15 Narukawa, Y., Kawakami, Y., Fujita, Sz., Fujita, Sg., and Nakamura, S., Phys. Rev. B rapid communication (to be published).Google Scholar
16. Smith, D. L and Mailhiot, C., Phys Rev Lett. 58, 1264 (1987).Google Scholar
17.The piezoelectric field was calculated with the values of piezoelectric constants of GaN (see Ref 1) according to Halsall, M. P., Nicholls, J. E., Davies, J. J, Cockayne, B., and Wright, P. J. [J. Appl. Phys. 71, 907 (1992)], and the Stark shift due to the electric field was calculated by the variational method neglecting exciton binding energy. Calculations are based on works by D. A Miller, D. S. Chemla, T. C. Damen, A C Gross, W Wiegmann, T. H. Wood, and C A. Burrus [Phys Rev Lett 53, 2173 (1981) and Phys Rev. B 32, 1043 (1985)].Google Scholar
18. Sugawara, M., Jpn. J. Appl. Phys. 35, 124 (1996).Google Scholar