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Recent Advances in Morphology and Mechanical Properties of Rigid-Rod Molecular Composites

Published online by Cambridge University Press:  21 February 2011

Stephen J. Krause  and
Wen-Fang Hwang
Stephen J. Krause
Affiliation:
Dept. of Chemical, Bio, and Materials Engineering, Arizona State University, Tempe, AZ 85287
Wen-Fang Hwang
Affiliation:
Dow Chemical Co., Central Research Laboratories - Advanced Polymeric Systems, Midland MI 48674
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Abstract

Rigid-rod molecular composites are a new class of high performance structural polymers which have high specific strength and modulus and also high thermal and environmental resistance. The concept of using a rigid-rod, extended chain polymer to reinforce a ductile polymer matrix at the molecular level has been demonstrated with morphological and mechanical property studies for aromatic heterocyclic systems, but new materials systems and processing techniques will be required to produce thermoplastic or thermoset molecular composites. Improved characterization and modeling will also be required. In this regard, new results on modeling of mechanical properties of molecular composites are presented and compared with experimental results. The Halpin-Tsai equations from ‘shear-lag’ theory of short fiber composites predict properties reasonably well when using the theoretical modulus of rigid-rod molecules in aromatic heterocyclic systems, but newer matrix systems will require consideration of matrix stiffness, desired rod aspect ratio, and rod orientation distribution. Application of traditional and newer morphological characterization techniques are discussed. The newer techniques include: Raman light scattering, high resolution and low voltage SEM, parallel EELS in TEM, synchrotron radiation in X-ray scattering, and ultrasound for integrity studies. The properties of molecular composites and macroscopic composites are compared and it is found that excellent potential exists for use of molecular composites in structural applications including engineering plastics, composite matrix resins, and as direct substitutes for fiber reinforced composites.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 171: Symposium O – Polymer Based Molecular Composites , 1989 , 131
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Helminiak, T.E., Arnold, F.E., and Benner, C.L., Am. Chem. Soc. Poly. Preprints, 16, 659 (1975).Google Scholar
2. Helminiak, T. E., Benner, C.L., Arnold, F., Husman, G., U.S. Pat. Appl. 902, 525 (1978).Google Scholar
3. Hwang, W-F., Wiff, D., Benner, C., Helminiak, T., J. Macromol. Sci. Phys., B22, 231 (1983).Google Scholar
4. Wolfe, J., “Polybenzthiazole and Polybenzoxazole Review” in Encyclopedia of Polymer Science and Engineering, 2nd Edition, J. Wiley & Sons, New York, 1988.Google Scholar
5. Husman, G., Helminiak, T.E., Adams, W.W., Wiff, D., and Benner, C.L., Am. Chem. Soc. Symp. Ser., 132, 203 (1980).Google Scholar
6. Christensen, R.M., Mechanics of Comnosite Materials, Wiley, New York, 1979.Google Scholar
7. Donaldson, S., private communication.Google Scholar
8. Flory, P.J., Proc. Roy. Soc. London, A234, 73 (1956).Google Scholar
9. Krause, S.J., Haddock, T., Price, G.E., Lenhert, P.G., O'Brien, J.F., Helniniak, T.E., and Adams, W.W., J. Polymer Sci. - Polym. Physics Edition, 24, 1991 (1986).Google Scholar
10. Day, R.J., Robinson, I.M., Zakikhani, M., and Young, R.J., Polymer, 24, 1833 (1988).Google Scholar
11. Young, R.J., private communication.Google Scholar
12. Hwang, W-F., Wiff, D., Verschoore, C., Price, G., Helminiak, T., and Adams, W.W., Poly. Eng. and Sci., 23, 784 (1983).Google Scholar
13. Tsai, T.T., Arnold, F.E., and Hwang, W.F., Am. Chem. Soc. Poly. Preprints, 26, 144 (1985).Google Scholar
14. Krause, S.J., Haddock, T.B., Lenhert, P.G., Hwang, W-F., Price, G., Helminiak, T.E., O'Brien, J.F., and Adams, W.W., Polymer, 22, 1353 (1988).Google Scholar
15. Hwang, W.F., Wiff, D.R., Helminiak, T.E., and Adams, W.W., ACS Preprints, Org. Coat. and Plast. Chem., 48, 922 (1983).Google Scholar
16. Wickliffe, S.M., Malone, M.F., and Farris, R.J., J. Appl. Polym. Sci., 34, 931 (1987).Google Scholar
17. Nehme, O., Gabriel, C., Farris, R.J., Thomas, E.L., and Malone, M., J. Appl. Polym. Sci., 35., 1955 (1988).Google Scholar
18. Krause, S.J. and Adams, W.W., Elect. Mic. Soc. Am. Proc., 46, 748 (1988).Google Scholar
19. Chauh, H.C., Kyu, T., and Helminiak, T.E., Am. Chem. Soc. Poly. Eng. Sci. Proc., 59, 1106 (1988)Google Scholar
20. Nishihara, T., Mera, H., and Matsuda, K., Am. Chem. Soc. Poly. Eng. Sci. Proc., 55, 821 (1986).Google Scholar
21. Chauh, H.C., Tan, L.S., and Arnold, F.E., Poly. Eng. and Sci., 29, 107 (1989).Google Scholar
22. Takayanagi, M., Ogata, T., Morikawa, M., Kai, T., J. Macro. Sci. Phys., B17, 519 (1980).Google Scholar
23. Krause, S.J., Adams, W.W., Kumar, S., Reilly, T., and Suzuki, T. Elect. Mic. Soc. Am. Proc., 45, 466 (1987).Google Scholar
24. Krause, S.J., Adams, W.W., and Joy, D.C., Elect. Mic. Soc. Am. Proc., 47, 336 (1989).Google Scholar
25. Krivanek, O.L., Elect. Mic. Soc. Am. Proc., 46, 660 (1988).Google Scholar