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Reactant Correlation Effects Study of Hydrogen Isotope Exchange Reaction on Supported Metal Catalysts

Published online by Cambridge University Press:  15 February 2011

Inchan Choi  and
Raoul Kopelman
Inchan Choi
Affiliation:
Department of Chemistry,University of Michigan, Ann Arbor, Michigan 48109
Raoul Kopelman
Affiliation:
Department of Chemistry,University of Michigan, Ann Arbor, Michigan 48109
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Abstract

Non-classical results due to reactant correlation effects have been observed in the study of Monte Carlo simulations of the A2 + B2 → 2AB reaction. These simulation results, interpreted by the Pair Density Analysis method and the experimental kinetic studies, may provide an explanation of the early time anomalous kinetic behavior of the catalytic hydrogen isotope exchange reaction exhibited for surface-diffusion limited conditions on alumina supported platinum islands.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 366: Symposium N – Dynamics in Small Confining Systems , 1994 , 325
Copyright
Copyright © Materials Research Society 1995

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References

1 Bond, G. C., ‘Catalysis by Metals’, Academic Press, London (1962).Google Scholar
2 Li, L., Ph. D. Thesis, The University of Michigan (1989).Google Scholar
3 Kopelman, R., SCIENCE, 241, 1620–1626 (1988).Google Scholar