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(Rare Earth/Li) Titanates and Niobates as Ionic Conductors

Published online by Cambridge University Press:  18 March 2011

A. Morata-Orrantia ,
S. García-Martín ,
E. Morán ,
U. Amador  and
M. A. Alario-Franco
A. Morata-Orrantia
Affiliation:
Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid-28040, Spain
S. García-Martín
Affiliation:
Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid-28040, Spain
E. Morán
Affiliation:
Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid-28040, Spain
U. Amador
Affiliation:
Departamento de Química Inorgánica y Materiales, Facultad de Ciencias Experimentales y Técnicas, Universidad San Pablo-CEU, Urb. Montepríncipe, 28668 Boadilla del Monte, Madrid, Spain
M. A. Alario-Franco
Affiliation:
Departamento de Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid-28040, Spain
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Abstract

The lithium ion conducting properties of materials of composition La0.58Li0.26TiO3, Nd0.58Li0.26TiO3, La0.67Li0.25Ti0.75Al0.25O3 and La0.29Li0.12NbO3 have been compared in relation with their microstructure. All the oxides have powder X-ray diffraction patterns characteristic of a perovskite-related structure with lattice parameters a∼√2ap, b∼√2ap, c∼2ap (p refers to cubic perovskite). However, some important differences are observed in their microstructure by SAED and HRTEM. Ordering between vacancies, Li+ and La3+ or Nd3+ and twinning of the NbO6 or TiO6 octahedra tilting system are shown in La0.29Li0.12NbO3 and Nd0.58Li0.26TiO3, which are the materials having a lower ionic conductivity. The La0.58Li0.26TiO3 and La0.67Li0.25Ti0.75Al0.25O3 oxides do not show ordering between cations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG2.3
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1. Inaguma, Y., Liquan, C., Itoh, M., Nakamura, T., Uchida, T., Ikuto, H. and Wakihara, M., Solid State Commun., 86, (1993), 689..Google Scholar
2. Kawai, H. and Kuwano, J., J. Electrochem. Soc., 141, (1994), 278..Google Scholar
3. Robertson, A. D., García-Martín, S., Coats, A. and West, A. R., J. Mater. Chem., 5(9), (1995), 1405.Google Scholar
4. Morales, M., West, A.R., Solid State Ionics 91 (1996) 33.Google Scholar
5. Inaguma, Y., Chen, L., Itoh, M. and Nakamura, T., Solid State Ionics, 70–71, (1994), 196..Google Scholar
6. Inaguma, Y. and Itoh, M., Solid State Ionics, 86–88, (1996), 257..Google Scholar
7. Harada, Y., Ishigaki, T., Kawai, H. and Kuwano, J., Solid State Ionics, 108, (1998), 407..Google Scholar
8.A. Vá rez, García-Alvarado, F., Morán, E. and Alario-Franco, M. A., J. Solid State Chem., 118, (1995), 78..Google Scholar
9. Skakle, J. M. S., Mather, G. C., Morales, M., Smith, R. I. and West, A. R., J. Mater. Chem. 5(9), (1995), 1807.Google Scholar
10. Fourquet, J. L., Duroy, H. and Crosnier-López, M. P., J. Solid State Chem., 127, (1996), 283..Google Scholar
11. García-Martín, S., García-Alvarado, F., Robertson, A. D., West, A. R. and Alario-Franco, M. Á., J. Solid State Chem. 128, (1997), 97.Google Scholar
12. Chung, H. T. and Cheong, D. S., Solid State Ionics, 120, (1999), 197..Google Scholar
13. Alonso, J. A., Sanz, J., Santamaría, J., León, C., Várez, A. and Fernández-Díaz, M. T., Angew. Chem. Int. Ed. 39(3), (2000), 619.Google Scholar
14. Shan, Y. J., Chen, L., Inaguma, Y., Itoh, M. and Nakamura, T., J. Power Sources 54, (1995), 397..Google Scholar
15. Bohnke, O., Bohnke, C. and Fourquet, J. L., Solid State Ionics 91, (1996), 21.Google Scholar
16. García-Martín, S., Rojo, J. M., Tsukamoto, H., Morán, E. and Alario-Franco, M. Á, Solid State Ionics 116, (1999), 11.Google Scholar
17. Alario-Franco, M. A., Grey, I. E., Joubert, J. C., Vincent, H. and Labeau, M., Acta Cryst. A 38, (1982), 177.Google Scholar
18. Labeau, M., Grey, I. E., Joubert, J. C., Vincent, H. and Alario-Franco, M. A., Acta Cryst. A 38, (1982), 753.Google Scholar
19. Labeau, M. Thesis, INPG, Grenoble, 1980.Google Scholar
20. García-Martín, S. and Alario-Franco, M. A., J. Solid State Chem. 148, (1999), 93.Google Scholar
21. Alario, M.A., Vallet, M., Henche, M. R., Calbet, J. M. G., Crenier, J. C., Wattiaux, A. and Hagenmuller, P., J. Solid State Chemistry, 46, 23, (1983).Google Scholar