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Radiation Stability of Crown Ether Used for Decontamination of Radionuclides from HLW

Published online by Cambridge University Press:  03 September 2012

Vyacheslav M. Abashkin
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
Gennadiy F. Egorov
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
Evgeniy Filippov
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
Anna K. Nardova
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
Igor V. Mamakin
Affiliation:
Russian Research Institute of Chemical Technology, 33 Kashirskoe Ave., Moscow 115230, [email protected]
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Abstract

The gamma-ray initiated oxidation of dicyclohexano-18-crown-6 (DCH-6) was studied in two-phase system under agitation: nitric acid, aqueous solution and organic solvent.

The distribution coefficients of radionuclides, hydrodynamic characteristics (phase separation and interface surface tension), and the radiolysis products after irradiation at a dose rate (60Co) of 1.7 Gy/s were determined. The maximum total dose was 3.O×105 Gy (3.0×107R).

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

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