Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-25T15:48:37.575Z Has data issue: false hasContentIssue false
  • English
  • Français

Pyridine N-Oxides As Polymeric Nonlinear Optical Materials

Published online by Cambridge University Press:  25 February 2011

Anselm C. Griffin ,
Amjad M. Bhatti  and
Greg A. Howell
Anselm C. Griffin
Affiliation:
Departments of Chemistry and Polymer Science, University of Southern Mississippi, Hattiesburg, MS 39406
Amjad M. Bhatti
Affiliation:
Departments of Chemistry and Polymer Science, University of Southern Mississippi, Hattiesburg, MS 39406
Greg A. Howell
Affiliation:
Departments of Chemistry and Polymer Science, University of Southern Mississippi, Hattiesburg, MS 39406
Get access

Abstract

Three polymers containing pyridine N-oxide imine pendant moieties were prepared and examined. Although the appropriate low molar mass model compound is liquid crystalline, the polymers are not mesogenic. Two of them form fibers and clear, transparent glasses. Side reactions involving the N-oxide group during polymerization are postulated as leading to the lack of mesomorphism in these materials although the π-chromophore remains essentially intact for the bulk of the material as judged by UV-Vis and other spectral data. They may have NLO application as poled polymeric glasses.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 109: Symposium K – Nonlinear Optical Properties of Polymers , 1987 , 115
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. a. Griffin, A. C., Bhatti, A. M. and Hung, R. S. L., Mol. Cryst. Liquid Cryst., in press.Google Scholar
b. Griffin, A. C., Bhatti, A. M. and Hung, R. S. L., in Nonlinear Optical and Electroactive Polymers, edited by Prasad, P. N. and Ulrich, D. R. (Plenum Publishing Corp., New York) in press.Google Scholar
c. Barny, P. Le, Ravaux, G., Dubois, J. C., Parneix, J. P., Njeumo, R., Legrand, C. and Levelut, A. M., Proceedings of SPIE, 682, 56(1987).Google Scholar
d. DeMartino, R. N., Choe, E. W., Khanarian, G., Haas, D., Leslie, T., Nelson, G., Stamatoff, J., Stuetz, D., Teng, C. C. and Yoon, H., in Nonlinear Optical and Electroactive Polymers, edited by Prasad, P. N. and Ulrich, D. R. (Plenum Publishing Corp., New York) in press.Google Scholar
e. DeMartino, R. N., Yoon, H. N., Stamatoff, J. B. and Buckley, A., U. S. Patent No. 4, 694, 006 (15 September 1987).Google Scholar
f. Griffin, A. C., Bhatti, A. M. and Hung, R. S. L., Proceedings of SPIE, 682, 65 (1987).Google Scholar
2. Fouquey, C., Lehn, J.-M. and Malthete, J., J. Chem. Soc., Chem. Commun. 1987, 1424.CrossRefGoogle Scholar
3. Bax, C. M., Katritzky, A. R. and Sutton, L. E., J. Chem. Soc. 1958, 1258.Google Scholar
4. Badan, J., Hierle, R., Perigaud, A. and Zyss, J. in Nonlinear Optical Properties of Organic and Polymeric Materials, edited by Williams, D. J. (American Chemical Society, Washington, DC, 1983), p. 81.Google Scholar
5. Zyss, J., Chemla, D. S. and Nicoud, J. F., J. Chem. Phys., 74, 4800 (1981).Google Scholar
6. Byron, D. J., Lacey, D. and Wilson, R. C., Mol. Cryst. Liquid Cryst., 75, 225 (1981).Google Scholar
7. Abreo, M. A., M.S. Thesis, University of Southern Mississippi, (1983).Google Scholar
8. Felder, E. and Pitre, D., Gazz. Chim. Ital., 86, 386 (1956).Google Scholar
9. Craig, J. C. and Purushothaman, K. K., J. Org. Chem., 35, 1721 (1970).Google Scholar
10. Mathes, W. and Sauermilch, W., Justus Liebigs Ann. Chem., 618, 152 (1958).Google Scholar
11. Vaidya, S. R., Ph.D. Dissertation, University of Southern Mississippi, (1986).Google Scholar
12. Abramovitch, R. A. and Smith, E. M., in Pyridine and Its Derivatives, Supplement, Part Two, edited by Abramovitch, R. A. (John Wiley and Sons, New York, 1974), p. 1.Google Scholar