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The Pseudostable Phase
Published online by Cambridge University Press: 26 February 2011
Abstract
The basic nature of kinetic processes is examined theoretically. When an isothermal development of order is studied theoretically, sometimes an ordered phase different from the final equilibrium one transiently predominates, while the free energy (Fsys) decreases monotonically although very slowly. There is another category of kinetic changes for which the convenient interpretation is that the Fsys surface itself changes in time. In this second category, a state can initially be a local minimum of Fsys and thus can be called a ‘metastable’ state, but after a certain time, as the Fsys surface itself changes, a kinetic path appears along which Fsys decreases and the system can change along it. To include both categories, the concept of the PSEUDOSTABLE phase is proposed. It is shown that even in the nucleation process, Fsys for the entire system decreases monotonically, although the local free energy may fluctuate.
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- Copyright © Materials Research Society 1992
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