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Proton infiltration of phosphosilicate glass-electrolytes for intermediate temperature fuel cell

Published online by Cambridge University Press:  15 January 2013

Yusuke Daiko ,
Takeshi Yamada ,
Atsushi Mineshige  and
Tetsuo Yazawa
Yusuke Daiko
Affiliation:
Department of Materials Science and Chemistry, University of Hyogo, 2167 Shosha, Himeji, 671-2280
Takeshi Yamada
Affiliation:
Department of Materials Science and Chemistry, University of Hyogo, 2167 Shosha, Himeji, 671-2280
Atsushi Mineshige
Affiliation:
Department of Materials Science and Chemistry, University of Hyogo, 2167 Shosha, Himeji, 671-2280
Tetsuo Yazawa
Affiliation:
Department of Materials Science and Chemistry, University of Hyogo, 2167 Shosha, Himeji, 671-2280
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Abstract

A fast proton conducting glass with proton transport number tH = 1 was successfully prepared by using conventional melting method. In-situ FTIR (Fourier transform infrared) measurements under hydrogen atmosphere, temperature of 300°C and applying 1 V between Pt electrodes were carried out in order to monitor the proton concentration. The electrode reaction on Pt in these conditions is similar to that under intermediate-temperature fuel cell operation. It was found from the in-situ FTIR measurements that the absorbance around 2900 cm-1 increases clearly after applying 1 V, whereas no significant change was observed around 3400 cm-1. Proton infiltration into the glass is discussed based on the in-situ FTIR and impedance results.

Keywords

ionic conductorion-solid interactionselectrical properties
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1495: Symposium I – Functional Materials for Solid Oxide Fuel Cells , 2013 , mrsf12-1495-i14-05
Copyright
Copyright © Materials Research Society 2013

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References

REFERENCES

Fergus, J. W., J. Power Sources, 162, 30 (2006).CrossRefGoogle Scholar
Jacobson, A. J., Chem. Mater., 22, 660 (2010).CrossRefGoogle Scholar
Sammells, A. F., Solid State Ionics, 52, 111 (1992).CrossRefGoogle Scholar
Daiko, Y. et al. ., Electrochem. Solid State Lett., 14, B63 (2011).CrossRefGoogle Scholar
Abe, Y. et al. ., J. Non-Cryst. Sol., 51, 357 (1982).CrossRefGoogle Scholar
Scholze, H., Naturwissenschaften, 47, 226 (1960) (in German).CrossRefGoogle Scholar
Ernsberger, F. M., Phys. Chem. Glasses, 21, 146 (1980).Google Scholar
Doremus, R. H., J. Electrochem. Soc., 15, 181 (1968).CrossRefGoogle Scholar
Wang, C. et al. ., J. Ceram. Soc. Jpn, 107, 1037 (1999).CrossRefGoogle Scholar
Takamatsu, Y. et al. ., (in submitting) Google Scholar