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Properties of Si/Cs/O nanocluster thin films with negative electron affinity

Published online by Cambridge University Press:  10 February 2011

L. N. Dinh
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA
W. McLean II
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA
M. A. Schildbach
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA
M. Balooch
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA
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Abstract

Thin films of Si/Cs/O nanoclusters have been synthesized by the technique of supersaturated thermal vaporization of Si and Cs in an oxygen background gas. These films, which were deposited onto conducting or semiconducting substrates, exhibit negative electron affinity (NEA) as evidenced by ultraviolet photoemission spectroscopy (UPS). Photo and field electron emission properties of these nanocluster films were investigated with photo-electron emission microscopy (PEEM), field electron emission microscopy (FEEM), and current-voltage measurements. Flat cathodes covered with thin films of Si/Cs/O nanoclusters exhibited high current outputs and low turn-on fields. The films' NEA is unaffected by air exposure and is stable to high temperature annealing (550 TC). A field emission display unit with a simple diode structure containing a flat cathode coated with a patterned thin film of Si/Cs/O nanoclusters has also been built to demonstrate the potential application of this material in cold cathode electron emitting devices, particularly field emission flat panel displays.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

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