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Production and Characterization of Deposited Mono-Sized Clusters

Published online by Cambridge University Press:  28 February 2011

Donald M. Cox
Affiliation:
Corporate Research Laboratories, Exxon Research and Engineering Company, Rt 22 East, Annandale, NJ 08801
Barbara Kessler
Affiliation:
Corporate Research Laboratories, Exxon Research and Engineering Company, Rt 22 East, Annandale, NJ 08801
Pierre Fayet
Affiliation:
Universite de Lausanne, Lausanne, Switzerland
Wolfgang Eberhardt
Affiliation:
Kernforschungsanlage, Julich, Germany.
Rex D. Sherwood
Affiliation:
Corporate Research Laboratories, Exxon Research and Engineering Company, Rt 22 East, Annandale, NJ 08801
Andrew Kaldor
Affiliation:
Corporate Research Laboratories, Exxon Research and Engineering Company, Rt 22 East, Annandale, NJ 08801
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Abstract

Using high energy rare gas ion sputtering of metal targets, we are able to produce nanoamps of mass selected transition metal clusters. Mono-sized cluster ions are deposited at low kinetic energy upon substrates, e.g. silica or carbon, and are then characterized using UV and x-ray photoemission. In this paper we will discuss photoemission measurements of the 4f7/2 core level energies of Au (1–5,7 atom samples) clusters deposited on silica. From such studies we are beginning to understand how electronic structure, cluster stability and mobility depend on (deposited) cluster size, surface coverage, and substrate temperature.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

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