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Pressure/Temperature/Reaction Phase Diagrams for Several Nitramine Compounds

Published online by Cambridge University Press:  15 February 2011

T. P. Russell
Affiliation:
Naval Surface Warfare Center Silver Spring, Maryland 20903–5000
P. J. Miller
Affiliation:
Naval Surface Warfare Center Silver Spring, Maryland 20903–5000
G. J. Piermarini
Affiliation:
Materials Science and Engineering Laboratory National Institute of Standards and Technology Gaithersburg, Maryland 20899
S. Block
Affiliation:
Materials Science and Engineering Laboratory National Institute of Standards and Technology Gaithersburg, Maryland 20899
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Abstract

Pressure/temperature/reaction phase diagrams for several nitramine compounds, including hexanitrohexaazaisowurtzitane (HNIW), 1,3,5-trinitrohexahydro-l,3,5-triazine (RDX), ammonium dinitramide (ADN), and p-nitroaniline (PNA) are presented. A diamond anvil cell was used in conjunction with optical polarizing light microscopy (OPLM), Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray diffraction (EDXD), and micro FT-Raman spectroscopy to determine these diagrams. A description is given of the diamond anvil cell and the associated techniques employed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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