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Preparation of Bi-Pb-Sr-Ca-Cu-O Superconductor By Thermal Decomposition of an Edta Colloid

Published online by Cambridge University Press:  28 February 2011

H.S. Koo
Affiliation:
Materials Research Laboratories, Industrial Technology Research Institute, Hsinchu, 31015, Taiwan, R.O.C.
C.K. Chiang
Affiliation:
Materials Research Laboratories, Industrial Technology Research Institute, Hsinchu, 31015, Taiwan, R.O.C.
Y.T. Huang
Affiliation:
Materials Research Laboratories, Industrial Technology Research Institute, Hsinchu, 31015, Taiwan, R.O.C.
G.C. Tu
Affiliation:
Institute of Materials Science and Engineering, National Chiao-Tung University, Hsinchu, 30049, Taiwan, R.O.C.
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Abstract

High-Tc superconducting Bi-Pb-Sr-Ca-Cu oxide with zero resistance temperature at above lOOK has been synthesized via the use of ethylenediamine-tetra-acetate(EDTA) colloid and corresponding metal nitrates. Remarkable sinterability of the precursor requires shorter time to achieve superconducting phases than conventional solid-state reactions. Superconducting properties were measured electrically and magnetically. The thermal decomposition, X-ray diffraction and microstructural characteristics of the precursor and the sintered samples were also discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

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