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Preparation and Characterization of Group 14 Element BIS(Thiolate) Compounds and Evaluation of Their Potential as Molecular Precursors in the Low Temperature Syntheses of Binary Metal Sulfides

Published online by Cambridge University Press:  22 February 2011

Gertrud KrÄuter ,
Philippe Favreau ,
Brian K. Nunnally  and
W. S. Rees JR.
Gertrud KrÄuter
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, F1 32306-3006
Philippe Favreau
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, F1 32306-3006
Brian K. Nunnally
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, F1 32306-3006
W. S. Rees JR.*
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, F1 32306-3006
*
address all correspondence to this author at: School of Chemistry and Biochemistry and School of Materials Research and Engineering, Georgia Instiute of Technology, Atlanta, Ga 30332-0400
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Abstract

Three isomeric lead bis(butylthiolate) and tin bis(butylthiolate) compounds have been prepared and characterized. Their solid state decomposition, and in the case of the lead bis(thiolate) compounds, their thermolyses in suspension in a high boiling hydrocarbon, have been studied. X-ray powder diffraction patterns and scanning electron micrographs of the obtained solid state material are discussed. Volatile co-products of the decomposition have been isolated and characterized.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 327: Symposium N – Covalent Ceramics II: Non-Oxides , 1993 , 41
Copyright
Copyright © Materials Research Society 1994

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References

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