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Preparation and Characterization of Group 12 Thiolate Complexes and Evaluation of Their Potential as Precursors for II-VI Semiconductors

Published online by Cambridge University Press:  28 February 2011

William S. Rees Jr ,
Gertrud Kräutern  and
Virgil L. Goedken
William S. Rees Jr
Affiliation:
Department of Chemistry, Florida State University, Tallahassee, FL 32306–3006 Materials Research and Technology Center, Florida State University, Tallahassee, FL 32306–3006
Gertrud Kräutern
Affiliation:
Department of Chemistry, Florida State University, Tallahassee, FL 32306–3006 Materials Research and Technology Center, Florida State University, Tallahassee, FL 32306–3006
Virgil L. Goedken
Affiliation:
Department of Chemistry, Florida State University, Tallahassee, FL 32306–3006
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Abstract

We have prepared compounds having the general formula M(SR)2 (M = Zn, Cd; R = i-Pr, t-Bu, Bz) and Hg(SR)CI (R = i-Pr, Bz) and investigated their use as potential sources in the preparation of metal sulfides from molecular precursors. Selected examples of the prepared compounds have been studied by single crystal x-ray diffraction. Decomposition has been carried out both in the solid state and by heating a suspension of a metal thiolate in a high boiling hydrocarbon. The decomposition products have been studied by GC/MS (liquids) and XRD (solids).

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 283: Symposium F – Microcrystalline Semiconductors–Materials Science and Devices , 1992 , 859
Copyright
Copyright © Materials Research Society 1993

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References

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