Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-27T01:44:28.906Z Has data issue: false hasContentIssue false
  • English
  • Français

Precursor Investigation in the Synthesis of PtPb Nanocatalysts

Published online by Cambridge University Press:  25 January 2013

Nathan Porter ,
Hong Wu ,
Minji Kong ,
Kai Sun ,
Amar Kumbhar  and
Jiye Fang
Nathan Porter
Affiliation:
Department of Chemistry and Materials Science & Engineering Program, State University of New York at Binghamton, Binghamton, New York 13902, United States
Hong Wu
Affiliation:
Department of Chemistry and Materials Science & Engineering Program, State University of New York at Binghamton, Binghamton, New York 13902, United States
Minji Kong
Affiliation:
Department of Chemistry and Materials Science & Engineering Program, State University of New York at Binghamton, Binghamton, New York 13902, United States
Kai Sun
Affiliation:
Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109, United States
Amar Kumbhar
Affiliation:
Chapel Hill Analytical and Nanofabrication Laboratory, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States
Jiye Fang*
Affiliation:
Department of Chemistry and Materials Science & Engineering Program, State University of New York at Binghamton, Binghamton, New York 13902, United States
*
*Email: [email protected]
Get access

Abstract

In recent years, platinum-based single crystalline nanoalloys as nanoscale catalysts, such as Pt-M (M = Ni, Co, Fe..etc.), have exhibited improved catalytic performance due to the increase in the surface-to-volume ratio. Some Pt-M nanopolyhedra such as nanocubes and nano-octahedra have been reported with enhanced activity when being used as electrocatalysts. In order to further establish a correlation between the exposed nanocrystal facets (shapes) and their corresponding activities, a pursuit of shape-controlled nanocatalyst synthesis is essential. Although PtPb nanoalloys have been prepared using solution-based methods, few studies have highlighted their catalytic activity as a function of the nanocrystal shape. This work focuses on a modified polyol synthesis technique and an adjustment of the Pb-metal precursor, which serves as a “buffer” in the nucleation stage of the shape-controlled nanoalloy development. Using this developed synthetic strategy, shape-controlled hexagonally close-packed PtPb nanoalloys can be prepared in a one-pot synthesis without additional post-treatment. The as-prepared PtPb nanocrystals demonstrate an improved anode electrocatalytic performance.

Keywords

chemical synthesiscrystallographic structurecatalytic
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1491: Symposium C – Electrocatalysis and Interfacial Electrochemistry for Energy Conversion and Storage , 2013 , mrsf12-1491-c07-09
Copyright
Copyright © Materials Research Society 2013

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Rabis, A., Rodriguez, P. and Schmidt, T. J., ACS Catal. 2 (5), 864–890 (2012).CrossRefGoogle Scholar
Sedha, R. S. K. R. S., Materials Science, S. Chand Limited, 2008.Google Scholar
Wagner, F. T., Lakshmanan, B. and Mathias, M. F., J. Phys. Chem. Lett. 1 (14), 2204–2219 (2010).CrossRefGoogle Scholar
Casado-Rivera, E., Volpe, D. J., Alden, L., Lind, C., Downie, C., Vázquez-Alvarez, T., Angelo, A. C. D., DiSalvo, F. J. and Abruña, H. D., J. Am. Chem. Soc. 126 (12), 4043–4049 (2004).CrossRefGoogle Scholar
Xu, D., Liu, Z., Yang, H., Liu, Q., Zhang, J., Fang, J., Zou, S. and Sun, K., Angew. Chem. Int. Ed. 48 (23), 4217–4221 (2009).CrossRefGoogle Scholar
Xu, D., Bliznakov, S., Liu, Z., Fang, J. and Dimitrov, N., Angew. Chem. Int. Ed. 49 (7), 1282–1285 (2010).CrossRefGoogle Scholar
Guo, M. Q., Wang, R. and Xu, X. H., Mater. Sci. Eng.: C 31 (8), 1700–1705 (2011).CrossRefGoogle Scholar
Zhang, J. and Fang, J., J. Am. Chem. Soc. 131 (51), 18543–18547 (2009).CrossRefGoogle Scholar
Kang, Y. and Murray, C. B., Journal of the American Chemical Society 132 (22), 7568–7569 (2010).CrossRefGoogle Scholar
Zhang, J., Yang, H., Fang, J. and Zou, S., Nano Lett. 10 (2), 638–644 (2010).CrossRefGoogle Scholar
Biacchi, A. J. and Schaak, R. E., ACS Nano 5 (10), 8089–8099 (2011).CrossRefGoogle Scholar
Liu, Y., Li, D., Stamenkovic, V. R., Soled, S., Henao, J. D. and Sun, S., ACS Catal. 1 (12), 1719–1723 (2011).CrossRefGoogle Scholar
Yin, A.-X., Min, X.-Q., Zhang, Y.-W. and Yan, C.-H., J. Am. Chem. Soc. 133 (11), 3816–3819 (2011).CrossRefGoogle Scholar
Kang, Y., Pyo, J. B., Ye, X., Gordon, T. R. and Murray, C. B., ACS Nano 6 (6), 5642–5647 (2012).CrossRefGoogle Scholar
Kang, Y., Qi, L., Li, M., Diaz, R. E., Su, D., Adzic, R. R., Stach, E., Li, J. and Murray, C. B., ACS Nano 6 (3), 2818–2825 (2012).CrossRefGoogle Scholar
Wu, J., Qi, L., You, H., Gross, A., Li, J. and Yang, H., J. Am. Chem. Soc. 134 (29), 11880–11883 (2012).CrossRefGoogle Scholar
Yu, D. and Yam, V. W.-W., J. Am. Chem. Soc. 126 (41), 13200–13201 (2004).CrossRefGoogle Scholar
Quan, Z., Luo, Z., Loc, W. S., Zhang, J., Wang, Y., Yang, K., Porter, N., Lin, J., Wang, H. and Fang, J., J. Am. Chem. Soc. 133 (44), 17590–17593 (2011).CrossRefGoogle Scholar
Wu, J., Zhang, J., Peng, Z., Yang, S., Wagner, F. T. and Yang, H., J. Am. Chem. Soc. 132 (14), 4984–4985 (2010).CrossRefGoogle Scholar
Zhang, S., Shao, Y., Liao, H., Liu, J., Aksay, I., Yin, G. and Lin, Y., Chem. Mater. 23 (5), 1079–1081 (2011).CrossRefGoogle Scholar
Niquirilo, R. V., Teixeira-Neto, E., Buzzo, G. S. and Suffredini, H. B., Int. J. Electrochem. Sci. 5, 344–354 (2010).Google Scholar