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Precision Teng-Man Electro-Optic Measurements Using Highly Near-Infrared Transparent Electrodes

Published online by Cambridge University Press:  01 February 2011

Lian Wang ,
Yu Yang ,
Zhifu Liu ,
Tobin J. Marks  and
Seng-Tiong Ho
Lian Wang
Affiliation:
[email protected], Northwestern University, Chemistry, Department of Chemistry, Northwestern University, Evanston, IL, 60201, United States, 224-622-0986, 847-491-3306
Yu Yang
Affiliation:
[email protected], Northwestern University, Department of Chemistry and the Materials Research Center, Evanston, IL, 60208-3113, United States
Zhifu Liu
Affiliation:
[email protected], Northwestern University, Department of Electrical and Computer Engineering, and the Materials Research Center, Evanston, IL, 60208-3113, United States
Tobin J. Marks
Affiliation:
[email protected], Northwestern University, Department of Chemistry and the Materials Research Center, Evanston, IL, 60208-3113, United States
Seng-Tiong Ho
Affiliation:
[email protected], Northwestern University, Department of Electrical and Computer Engineering, and the Materials Research Center, Evanston, IL, 60208-3113, United States
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Abstract

A series of highly near-infrared (NIR) transparent In2O3 thin films has been grown by ion-assisted deposition (IAD) at room temperature, and their optical and electrical properties characterized. The NIR transparency and the plasma edge can be engineered through control of the film deposition conditions. The as-deposited In2O3 thin films were employed as transparent electrodes for direct electro-optic (EO) characterization measurements via the Teng-Man technique. Using LiNbO3 as the standard, the relationship between the degree of electrode NIR transparency and Teng-Man EO measurement accuracy was evaluated. It is found that In2O3 electrodes can be tailored to be highly NIR transparent, thus providing more accurate Teng-Man EO coefficient quantification than ITO (tin-doped indium oxide). In addition, the EO coefficients of stilbazolium-based self-assembled superlattice (SAS) thin films were directly determined for the first time by the Teng-Man technique using an optimized In2O3 electrode. EO coefficients r33 of 42.2, 13.1, and 6.4 pm/V are obtained at 633, 1064, and 1310 nm, respectively.

Keywords

transparent conductoroptical propertieselectrical properties
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 928: Symposium GG – Current and Future Trends of Functional Oxide Films , 2006 , 0928-GG09-08
Copyright
Copyright © Materials Research Society 2006

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References

1 Teng, C. C. and Man, H. T., Appl. Phys. Lett. 56, 1734 (1990).Google Scholar
2 Shuto, Y. and Amano, M., J. Appl. Phys. 77, 4632 (1995).Google Scholar
3 Schildkraut, J. S., Appl. Opt. 29, 2839 (1990).Google Scholar
4 Michelotti, F., Belardini, A., Larciprete, M. C., Bertolotti, M., Rousseau, A., Ratsimihety, A., Schoer, G. and Mueller, J., Appl. Phys. Lett. 83, 4477 (2003).Google Scholar
5 Hartnagel, H. L., Dawar, A. L., Jain, A. K. and Jagadish, C., Semiconducting Transparent Thin Films, (Iop Institute of Physics, November 1, 1995), p 273.Google Scholar
6 Chollet, P. A., Gadret, G., Kajzar, F. and Raimond, P., Thin Solid Films 242, 132 (1994).Google Scholar
7 Yang, Y., Huang, Q. L., Metz, A. W., Ni, J., Jin, S., Marks, T. J., Madsen, M. E., DiVenere, A. and Ho, S. T., Adv. Mater. 16, 321 (2004).Google Scholar
8The standard value is independently measured by MTI Crystal Corporation.Google Scholar
9 Zhu, P. W., Boom, M. E. van der, Kang, H., Evmenenko, G., Dutta, P. and Marks, T. J., Chem. Mater. 14, 4982 (2002).Google Scholar
10 Ho, S. T., Liu, Z., Ma, J., Xu, G., Liu, B., Marks, T. J., Zhu, P. W., Kang, H. and Facchetti, A., Proc. GOMACTech, 231 (2004).Google Scholar
11 Kalluri, S., Garner, S., Ziari, M., Steier, W. H., Shi, Y. and Dalton, L. R., Appl. Phys. Lett. 69, 275 (1996).Google Scholar
12 Nalwa, H. S. and Miyata, S., Nonlinear Optics of Organic Molecules and Polymers, (CRC Press, 1996), p 397.Google Scholar
13 Lundquist, P. M., Lin, W., Zhou, H., Hahn, D. N., Yitzchaik, S., Marks, T. J. and Wong, G. K., Appl. Phys. Lett. 70, 1941 (1997).Google Scholar