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Porous Metal Oxides as Catalysts

Published online by Cambridge University Press:  21 May 2012

Boxun Hu ,
Christopher Brooks ,
Eric Kreidler  and
Steven L. Suib
Boxun Hu
Affiliation:
Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USA.
Christopher Brooks
Affiliation:
Honda Research Institute USA, Inc. 1381 Kinnear Rd. Suite 116, Columbus, OH 43212, USA.
Eric Kreidler
Affiliation:
Honda Research Institute USA, Inc. 1381 Kinnear Rd. Suite 116, Columbus, OH 43212, USA.
Steven L. Suib
Affiliation:
Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USA. Department of Chemistry, University of Connecticut, Storrs, CT 06269, USA.
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Abstract

Porous CoO/Mn2O3 Fischer-Tropsch (F-T) catalysts have been studied in CO hydrogenation. These CoO/Mn2O3 catalysts have been synthesized by incipient wetness impregnation method. These mesoporous catalysts have pore diameters of 2-25 nm and a surface area of 9.0 m2/g. The gas and liquid products have been analyzed by an online gas chromatograph. The solid products were characterized by gas chromatograph-mass spectroscopy. These microsize cobalt catalysts exhibit good activity with 72.1% CO conversion and they are very stable in a 48 h stream test at 280ºC. The selectivity to paraffins is above 95%. Few wax products were synthesized with a yield of less than 2%. The size effects of the cobalt catalysts have been studied by scanning electron microscopy.

Keywords

catalyticMnCo
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1446: Symposium U – Materials for Catalysis in Energy , 2012 , mrss12-1446-u08-07
Copyright
Copyright © Materials Research Society 2012

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References

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