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Polymer-on-Polymer Stamping on Micro- and Nano-Scales

Published online by Cambridge University Press:  11 February 2011

Shoshana Gourdin
Affiliation:
Massachusetts Institute of Technology, Department of Chemical Engineering, Cambridge, Massachusetts 02139
Travis Crites
Affiliation:
West Virginia University, Department of Chemical Engineering, Morgantown, West Virginia 26506
Seth Coe
Affiliation:
Massachusetts Institute of Technology, Department of Electrical Engineering and Computer Science, Cambridge, Massachusetts 02139
Vladimir Bulovic
Affiliation:
Massachusetts Institute of Technology, Department of Electrical Engineering and Computer Science, Cambridge, Massachusetts 02139
Paula Hammond
Affiliation:
Massachusetts Institute of Technology, Department of Chemical Engineering, Cambridge, Massachusetts 02139
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Abstract

The goal of the project was to determine whether PDAC (poly (diallyldimethylammonium chloride), also abbreviated PDADMAC) could be printed reproducibly to create patterns with a sub-micron resolution. PDAC was stamped onto bare silicon using PDMS stamps having features only about 150 nm wide. A variety of aqueous PDAC inks were tried, to study the effect of concentration and ionic strength on the pattern produced. In order to get good prints, new stamping techniques were also required. A rigid stamping apparatus was built to ensure steady placement, and the stamps were spin coated with a different ink solution to produce thin, even coats of ink. [1] Using these methods, the pattern transferred.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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References

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