Hostname: page-component-745bb68f8f-hvd4g Total loading time: 0 Render date: 2025-02-05T05:52:16.480Z Has data issue: false hasContentIssue false
  • English
  • Français

Poly-β-Cyclodextrins: Multifunctional Polymer Support for the Hydrolysis and Removal of Methyl Parathion

Published online by Cambridge University Press:  15 February 2011

Yongwoo Lee  and
Alok Singh
Yongwoo Lee
Affiliation:
Center for Bio/Molecular Science & Engineering, Naval Research Laboratory 4555 Overlook Ave.Washington, DC 20375
Alok Singh
Affiliation:
Center for Bio/Molecular Science & Engineering, Naval Research Laboratory 4555 Overlook Ave.Washington, DC 20375
Get access

Abstract

Microparticles (32-53 μm) of cross-linked poly-β-Cyclodextrin (PCD) having a bifunctional hexyl spacer were prepared. PCD served as an insoluble robust matrix, which is chemically inert in acidic and basic media while preserving accessibility of pesticide methyl parathion (MPT) and its hydrolysis product p-nitrophenol (p-NP) to cyclodextrin cavities. The multi-utility of PCD was demonstrated as a stable biomaterial for adsorption of MPT and p-NP through inclusion phenomena and as a single unit system suitable for casting alternate enzyme/polyelectrolyte multilayers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 774: Symposium O – Materials Inspired by Biology , 2003 , O7.32
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Decher, G., Science 227, 1232–1237 (1997).Google Scholar
2. Sukhorukhov, G. B. Donath, E. Davis, S. Lichtenfeld, H. Caruso, F. Popov, V. L. and Möhwald, H., Polym. Adv. Technol. 9, 759–767 (1998)Google Scholar
3. Caruso, F. and Schuler, C. Langmuir 16, 9595–9603 (2000).Google Scholar
4. Lvov, Y. and Caruso, F. Anal. Chem. 73, 4212–4217 (2001).Google Scholar
5. Santos, J. P, Welsh, E. R. Gaber, B. P. and Singh, A. Langmuir 17, 5361–5367 (2001).Google Scholar
6. Lee, Y. Stanish, I. Rastogi, V. Cheng, T.-c., and Singh, A. Langmuir 19, 1330–1336 (2003).Google Scholar
7. Szejtli, J. Chem. Rev. 98, 1743–1753 (1998).Google Scholar
8. Bertrandm, G. L. Faulkner, J. R. Jr, Han, S. M. and Armstrong, D. W. J. Phys. Chem. 93, 6863–6867 (1989).Google Scholar
9. Li, D, Ma, M. Chemtech, 31–36 (May, 1999).Google Scholar