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Poly (L,4-Naphthylene Sulfide) Oligomers: Electronic And Vibrational Spectra Of The Pristine And Oxidized Forms

Published online by Cambridge University Press:  16 February 2011

P. Piaggio ,
G. Petrillo ,
M. Novi  and
C. Dell'Erba
P. Piaggio
Affiliation:
University of Genova, Istituto di Chimica Industriale, C. so Europa 30, 16132 Genova, Italy
G. Petrillo
Affiliation:
University of Genova, Istituto di Chimica Organica and CNR Centro di Studio per la Chimica dei Composti Cicloalifatici ed Aromatici, C.so Europa 26, 16132 Genova, Italy
M. Novi
Affiliation:
University of Genova, Istituto di Chimica Organica and CNR Centro di Studio per la Chimica dei Composti Cicloalifatici ed Aromatici, C.so Europa 26, 16132 Genova, Italy
C. Dell'Erba
Affiliation:
University of Genova, Istituto di Chimica Organica and CNR Centro di Studio per la Chimica dei Composti Cicloalifatici ed Aromatici, C.so Europa 26, 16132 Genova, Italy
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Abstract

New naphthalene-sulfur compounds, oligomers of poly (l,4-naphthylene sulfide), have been synthesized and studied by electronic and vibrational spectroscopy in both pristine and oxidized forms. It has been found that the charged defects induced on these molecules are Much More stable than in the corresponding 1,4-phenylene derivatives. Nevertheless their physical properties are strongly affected by steric effects which hinder a regular arrangement of the repeating units.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 325
Copyright
Copyright © Materials Research Society 1994

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References

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