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Plasma Assisted Oxidation of Si at Temperatures below 800°C

Published online by Cambridge University Press:  28 February 2011

C. K. Williams
Affiliation:
Microelectronics Center of North Carolina, P.O.Box 12889, Research Triangle Park, NC 27709
A. Reismanu
Affiliation:
Microelectronics Center of North Carolina, P.O.Box 12889, Research Triangle Park, NC 27709 Department of Electrical and Computer Engineering, Box 7911, North Carolina State University, Raleigh, NC 27695-7911
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Abstract

A system for plasma assisted oxidation of Si at temperatures below 800°C is described.Oxides grown in this system have an unusual thickness versus time relationship.The first 110 nm of oxide exhibit a t1/2 dependence.Any additional growth shows a t1/3 dependence.Pressure, oxygen concentration, and rf power are all important parameters in determining the growth rate and uniformity of the oxide layers.Breakdown measurements on these oxide layers show that post oxidation annealing is necessary if these oxides are to compete with thermal oxides.The type of annealing is very important in determining the breakdown voltage.The results of various annealing procedures are described.The effects of heating the wafers independent of the heat generated by the plasma, and the frequency dependence of the growth are discussed.

Type
Articles
Copyright
Copyright © Materials Research Society 1986

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References

1. Reisman, A., Proc.IEEE 71, 550 (1983).Google Scholar
2. Deal, B.E., Grove, A.S., Snow, E.H., and Sah, C.T., J.Electrochem.Soc. 112, 308 (1965).CrossRefGoogle Scholar
3. Hu, S.M., J.Appl.Phys. 45, 1567 (1974).Google Scholar
4. Murarka, S.P., J.Appl.Phys., 48, 5020 (1977).CrossRefGoogle Scholar
5. Bassous, E., Yu, H.N., and Maniscalco, V., J.Electrochem.Soc. 123, 1729 (1976).CrossRefGoogle Scholar
6. Ray, A.K. and Reisman, A., J.Electrochem.Soc., 128 2460 (1981).Google Scholar
7. Ray, A.K. and Reisman, A., J.Electrochem.Soc., 128 2466 (1981).Google Scholar
8. Ligenza, J.R., J.Appl.Phys. 36, 2703 (1965).Google Scholar
9. Kraitchman, J., J.Appl.Phys., 38, 4323 (1967).Google Scholar
10. Skelt, E.R. and Howells, G.M., Surface Science 7, 490 (1967).Google Scholar
11. O'Hanlon, J.F., J.Vac.Sci.and Technol. 7, 330 (1970).Google Scholar
12. Gourrier, S., Mircea, A., and Bacal, M., Thin Solid Films 65, 315 (1980).Google Scholar
13. Orcutt, W.B., M.S.Thesis, Air Force University, Faculty of the School of Engineering, Air Force Institute of Technology, (1972).Google Scholar
14. Ligenza, J.R. and Kuhn, M., Solid State Technol., Dec.1970, p.33.Google Scholar
15. Pulfrey, D.L., Hathorn, F.G.M. and Young, L., J.Electrochem.Soc. 120, 1529 (1973).CrossRefGoogle Scholar
16. Matsuzawa, A., Itoh, T., Ishikawa, Y. and Yanagida, H., J.Vac.Sci.Technol. 17, 793 (1980).CrossRefGoogle Scholar
17. Sagano, T., Thin Solid Films 92, 19 (1982).Google Scholar
18. Reisman, A., Proc.of the 51h International Symposium on Silicon Material Science and Technology, Electrochemical Society Spring Meeting, May 4-9, 1986, Boston, MA.(in press).Google Scholar
19. Srivastava, J.K., Irene, E.A., Lucovsky, G. and Martin, M J., presented at the March meeting of The American Physical Society, March 31-April 4.1986, Las Vegas, Nevada.Google Scholar