Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-29T07:35:42.709Z Has data issue: false hasContentIssue false

Physical and Chemical Properties of Silicon Dioxide Film Deposited by New Process

Published online by Cambridge University Press:  22 February 2011

Takuji Goda
Affiliation:
Central Research Laboratory, Nippon Sheet Glass Co., Ltd., Konoike, Itami, Hyogo, Japan
Hirotsugu Nagayama
Affiliation:
Central Research Laboratory, Nippon Sheet Glass Co., Ltd., Konoike, Itami, Hyogo, Japan
Akihiro Hishinuma
Affiliation:
Central Research Laboratory, Nippon Sheet Glass Co., Ltd., Konoike, Itami, Hyogo, Japan
Hideo Kawahara
Affiliation:
Central Research Laboratory, Nippon Sheet Glass Co., Ltd., Konoike, Itami, Hyogo, Japan
Get access

Abstract

A new coating process of silicon dioxide (SiO2) “LPD” process, has been developed recently. Silicon dioxide (SiO2) film can be deposited on any substrate at the room temperature by immersing in hexafluorosilicic acid (H2SiF6).

In this study, physical and chemical properties of the “LPD- SiO2” film were investigated by using XPS, IR, ellipsometry, and etch rate measurement. The properties of this film deposited at the room temperature were almost the same as those of plasma CVD. The “LPD-SiO2” film without annealing was contained traces of F and OH. However, by annealing, F and OH were rapidly evaporated from the film and the film was getting densified.

As the “LPD-SiO2” film deposited at the room temperature showed very good results of chemical etching rate and of step coverage, it is expected that it is possible to use this “LPD- SiO2” film in the wide range of industrial area.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Orlowski, T. E. and Richter, H., Appl. Phys. Lett. 45, 241 (1984)Google Scholar
2. Okuyama, M., Toyoda, Y. and Hamakawa, Y., Jpn. J. Appl. Phys. 23, L97 (1984)CrossRefGoogle Scholar
3. Serikawa, T. and Yachi, T., J. Electrochem. Soc. 131, 2105 (1984)Google Scholar
4. Lucovsky, G., Monitini, M. J., Srivastava, J. K. and Irene, E. A., J. Vac. Sci. Technol. B 5, 530 (1987)CrossRefGoogle Scholar
5. Nagayama, H., Honda, H. and Kawahara, H., presented at Amer. Ceram. Soc. 87th Annual Meeting, Cincinnati, Ohio 1985 Google Scholar
6. Nagayama, H., Honda, H. and Kawahara, H., J. Electrochem. Soc., to be publishedGoogle Scholar
7. Pliskin, W. A., J. Vac. Sci. Technol. 14, 1064 (1977)Google Scholar
8. Pliskin, W. A. and Lehman, H. S., J. Electrochem. Soc. 112, 1013 (1965)Google Scholar
9. Deal, B. E. and Grove, A. S., J. Appl. Phys. 36, 3770 (1965)Google Scholar
10. Wagner, C. D., Riggs, W. M., Davis, L. E. and Moulder, J. F. in Handbook of X-ray Photoelectron Spectroscopy, edited by Muilenberg, G. E. (Perkin-Elmer Corporation Physical Electronics Division, Eden Praire, Minn. 1979) p. 52 Google Scholar
11. Ritter, E., Opt. Acta 9, 197 (1962)Google Scholar
12. Yanagawa, H., Hashimoto, N. and Ashikawa, M., Oyo butsuri 43, 330 (1974) (in Japanese)Google Scholar
13. Krol, D. M. and Rabinovich, E. M., J. Non-Cryst. Solids 82, 143 (1986)Google Scholar