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Photochromic-Induced Photorefractive Changes in Barium Titanate

Published online by Cambridge University Press:  21 February 2011

M. H. Garrett
Affiliation:
Center for Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Ave. Rm 13–3157, Cambridge, MA 02139
J. Y. Chang
Affiliation:
Departments of Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Ave. Rm 13–3157, Cambridge, MA 02139
H. P. Jenssen
Affiliation:
Center for Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Ave. Rm 13–3157, Cambridge, MA 02139
C. Warde
Affiliation:
Electrical Engineering and Computer Science, Massachusetts Institute of Technology, 77 Massachusetts Ave. Rm 13–3157, Cambridge, MA 02139
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Abstract

Photochromism in barium titanate was found to affect its deep and shallow trap properties. Argon ion laser illumination at 514.5 nm photo-induced semi-permanent (thermally reversible) changes in the visible absorption spectrum of barium titanate that were stable at room temperature. Increases in absorption at 514.5 nm, also the operating wavelength used to determine photorefractive properties, caused a decrease in the photorefractive response time but also a decrease in the sensitivity. When the photochromism was inactive the crystal shows light-induced absorption. With the photochromism saturated the crystal showed light-induced transparency. A model with two photoactive levels is used to characterize the photorefractive properties of this photochromic crystal.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

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