Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-04T21:49:14.472Z Has data issue: false hasContentIssue false
  • English
  • Français

PEMFC Development at Asahi Glass Co., Ltd.

Published online by Cambridge University Press:  10 February 2011

M. Yoshitake ,
E. Yanagisawa ,
T. Naganuma  and
Y. Kunisa
M. Yoshitake
Affiliation:
Chemistry Research Laboratory, Asahi Glass Co., Ltd., Yokohama, 221–8755, [email protected]
E. Yanagisawa
Affiliation:
Chemistry Research Laboratory, Asahi Glass Co., Ltd., Yokohama, 221–8755, [email protected]
T. Naganuma
Affiliation:
Chemistry Research Laboratory, Asahi Glass Co., Ltd., Yokohama, 221–8755, [email protected]
Y. Kunisa
Affiliation:
Chemistry Research Laboratory, Asahi Glass Co., Ltd., Yokohama, 221–8755, [email protected]
Get access

Abstract

Perfluorinated ion exchange membranes were studied and the membrane technology for PEMFC has been developed. Thermal stability, mechanical strength, water content, AC specific resistance and gas permeability were measured. The influence of membrane thickness on gas permeability and the influence of incorporation of cations on water content and AC specific resistance of Flemion® and Nafion® 117 were estimated. Gas permeation rates of the membranes decreased in inverse proportion to the increase of the membrane thickness and gas permeability coefficients were nearly constant and independent of the thickness. Hydrogen permeation rates of Flemion®S at 70°C were converted to 2.1 mA/cm2 as cunent density. Flemion®R-electrode assembly showed to maintain stable perfonnance for over 3,500hr. Furthermore, it was found that usage of thinner membranes or one with higher ion-exchange capacity gave not only lower intemal cell voltage but also higher iR-free cell voltage. PTFE-yam embedded type membrane (Flemion®Mc and Sc) and PTFE-flbril dispersed type (Flemion®R12) was examined to afford improvement in mechanical strength at moist and high temperature atmosphere. Flemion®Sc (80!am) was examined to give high cell performance of 0.67V at 0.5A/cm2, 80°C, I ata. Flemior®Mc-electrode assembly was examined to keep stable performance during the life test of over 1,500hr.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 575: Symposium CC – New Materials for Batteries & Fuel Cells , 1999 , 213
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1) Yoshitake, M., Tamura, M. and Ishisaki, T., FCDIC 1'st Symposium, 154(1994).Google Scholar
2) Yoshida, N., Ishisaki, T. and Yoshitake, M., FCDIC 2'nd Symposium, 220(1995).Google Scholar
3) Yoshitake, M., Yoshida, N. and Ishisaki, T., FCDIC 3'rd Symposium, 296(1996).Google Scholar
4) Fuel Cell Development Information Center: Fuel Cell RD& D in Japan, 130(1995).Google Scholar
5) Fuel Cell Development Information Center: Fuel Cell RD& D in Japan, 130(1996).Google Scholar
6) Yoshitake, M., Tamura, M., Yoshida, N. and Ishisaki, , Denkikagaku, 64, 727(1996).Google Scholar
7) Gierke, T. D., Munn, G. E. and Wilson, F. C., J Polym. Sci, 19,1687(1981).Google Scholar
8) Wu, D. Q., Ling, B. and Chu, B., Proceedings of 15th Soda Kogyo Gijutu Toronkai, 79(1981).Google Scholar
9) Sakai, T., Takenaka, H. and Torikai, E., J Electrochem.Soc., 133,88 (1986).Google Scholar
10) Wakizoe, M., Kim, J. and Srinivasan, S., Proc., Electrochem. Soc., 183rd Society Meeting, 93–98, 310(1993).Google Scholar
11) Chiou, J. S. and Paud, D. R., Ind Eng. Res., 27, 2161(1988).Google Scholar
12) Okuyama, K and Nishikawa, F., Nippon Kagakukaishi (in Japanese), 1994, 1091.Google Scholar
13) Yawataya, T., Enjinia no tame no ionkoukanmaku, (in Japanese) Kyouritu Shuppan, Tokyo, p.68, 1982.Google Scholar
14) Fontanella, J. J., McLin, M. G. and Wintersgill, M. C., Soid State Ionics., 66,1 (1993).Google Scholar
15) Cahan, B. D. and Weinright, J. S., J Elctvrochem. Soc., 140, L185 (1993).Google Scholar
16) Yoshitake, M., Yoshida, N. and Ishisaki, T., Program and Abstracts of 1996 Fuel Cell Seminar, 509(1996), Orlando.Google Scholar
17) Perfluorinated Ionomer Membranes, ACS. Symp. Ser 180 (Ed. Eisenberg, A. and Yeager, H. L.) (1982).Google Scholar
18) Hinatsu, J. T., Mizuhata, M. and Takenaka, H., J Electrcwhem. Soc., 141, 1493(1994).Google Scholar