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Patterning biopolymer surfaces by enzymatic soft lithography

Published online by Cambridge University Press:  06 September 2011

A. Guyomard-Lack ,
C. Moreau ,
N. Delorme ,
J.-F. Bardeau  and
B. Cathala
A. Guyomard-Lack
Affiliation:
UR 1268 Biopolyméres, Interactions et Assemblages, 44316 Nantes, France
C. Moreau
Affiliation:
UR 1268 Biopolyméres, Interactions et Assemblages, 44316 Nantes, France
N. Delorme
Affiliation:
Laboratoire de Physique de l’Etat Condensé, UMR CNRS 6087, Institut de Recherche en Ingénierie Moléculaire et Matériaux Fonctionnels (FR2575), Université du Maine 72085 Le Mans, France
J.-F. Bardeau
Affiliation:
Laboratoire de Physique de l’Etat Condensé, UMR CNRS 6087, Institut de Recherche en Ingénierie Moléculaire et Matériaux Fonctionnels (FR2575), Université du Maine 72085 Le Mans, France
B. Cathala
Affiliation:
UR 1268 Biopolyméres, Interactions et Assemblages, 44316 Nantes, France
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Abstract

A novel rapid and easy-to-use method for patterning surfaces on large scale is described. Micro-patterns were created by direct contact of trypsin-functionalized poly(dimethylsiloxane) (PDMS) stamps with poly-L-lysine (PLL) layer adsorbed on silicon surface. The catalytic process does not involve ink transfer and thus lateral diffusion is avoided. As a result duplication of the stamp pattern is highly enhanced comparatively to standard microcontact printing procedure where PLL is used as ink and transferred on silicon surface. Patterning was revealed by fluorescence microscopy and atomic force microscopy (AFM). Adsorption on the patterned surfaces of cellulose nanocrystals was investigated as an example of application.

Keywords

thin filmlithography (removal)surface chemistry
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1340: Symposium T – High-Speed and Large-Area Printing of Micro/Nanostructures and Devices , 2011 , mrss11-1340-t02-04
Copyright
Copyright © Materials Research Society 2011

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References

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