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Oxygen potentials of PuO2-x

Published online by Cambridge University Press:  13 June 2012

Akira Komeno ,
Masato Kato ,
Shun Hirooka  and
Takeo Sunaoshi
Akira Komeno
Affiliation:
Advanced Nuclear System Research and Development Directorate, Japan Atomic Energy Agency, 4-33 Muramatsu, Tokai-mura, Naka-gun, Ibaraki 319-1194, Japan
Masato Kato
Affiliation:
Advanced Nuclear System Research and Development Directorate, Japan Atomic Energy Agency, 4-33 Muramatsu, Tokai-mura, Naka-gun, Ibaraki 319-1194, Japan
Shun Hirooka
Affiliation:
Advanced Nuclear System Research and Development Directorate, Japan Atomic Energy Agency, 4-33 Muramatsu, Tokai-mura, Naka-gun, Ibaraki 319-1194, Japan
Takeo Sunaoshi
Affiliation:
Inspection Development Company, 4-33 Muramatsu, Tokai-Mura, Ibaraki 319-1194, Japan
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Abstract

Oxygen potentials of PuO2-x were measured at temperatures of 1473 - 1873 K by thermo-gravimetry. The oxygen potentials were determined by in situ analysis as functions of oxygen-to-metal ratio and temperature. The measurement data were analyzed on the basis of defect chemistry and an approximate equation was derived to represent the relationship among temperature, oxygen partial pressure, and deviation x in PuO2-x.

Keywords

Puoxidethermogravimetric analysis (TGA)
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1444: Symposium S/Y – Actinides and Nuclear Energy Materials , 2012 , mrss12-1444-y06-01
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

1. Sari, C., Benedict, U., Blank, H., J. Nucl. Mater. 35 (1970) 267–277.Google Scholar
2. Markin, T.L., Street, R.S., J. Inorg. Nucl. Chem. 29 (1967) 2265–2280.Google Scholar
3. Kato, M., Konashi, K., J. Nucl. Mater. 385(2009) 117–121 Google Scholar
4. Morimoto, K., Kato, M., Ogasawara, M., Kashimura, M., J. Nucl. Mater. 374(2008) 378–385 Google Scholar
5. Kato, M., Morimoto, K., Nakamichi, S., Sugata, H., Konashi, K., Kashimura, M., Abe, T., Trans. Atom. Ener. Soc. Japan 7 [4] (2008) 420–428 (in Japanese).Google Scholar
6. Markin, T.L., McIver, E.J., in: Plutonium 1965, Barnes and Noble, New York, 1967, p. 845.Google Scholar
7. The Plutonium-Oxygen and Uranium-Plutonium-Oxygen Systems: A Thermochemical Assessment, Tech. Report Ser. No.79, IAEA, Vienna, 1967, p. 52.Google Scholar
8. Woodley, R.E., J. Nucl. Mater. 96 (1981) 5–14 Google Scholar
9. Sorensen, O.T., in: Plutonium and Other Actinides, Elsevier, New York, 1976, p.123 Google Scholar
10. Chilton, G.R., Kirkham, I.A., United Kingdom Atomic Energy Authority Northern Division Report, ND-R-R98(W), 1973 Google Scholar
11. Vasudeva Rao, P.R., Anthonysamy, S., Krishnaiah, M.K., Chandramouli, V., J. Nucl. Mater. 348 (2006) 329–334 Google Scholar
12. Kato, M., Tamura, T., Konashi, K., Aono, S., J. Nucl. Mater. 344 (2005) 235–239 Google Scholar
13. Kato, M., Tamura, T., Konashi, K., J. Nucl. Mater. 385 (2009) 419–423 Google Scholar
14. Kato, M., Nakamichi, S., Takeuchi, K., Sunaoshi, T., CALPHAD, doi:10.1016/j.calphad.2011.02.007 Google Scholar
15. Kato, M., Takeuchi, K., Uchida, T., Sunaoshi, T., Konashi, K., J. Nucl. Mater., doi:10.1016/j.jnucmat.2011.01.042 Google Scholar
16. Woodley, R.E., J. Nucl. Matr. 96(1981) 5–14 Google Scholar
17. Swanson, G.C., Report, LA-6083-T (1975)Google Scholar
18. Markin, T.L., Bones, R.J., Gardner, E.R., U.K.E.A. Report, AERE-R 4724 (1964)Google Scholar
19. Atlas, L.M., Schlehman, G.J., IAEA-SM-66/79 (1966) 407 Google Scholar
20. Kubaschewski, O., Alcock, C.B., Metallugical Thermochemistry, 5th Ed., Pergamon, 1979 Google Scholar
21. Brouwer, G., Philips Res. Rep. 9 (1954) 366–376 Google Scholar
22. Kroger, F.A., Vink, H., Solid State Physics, Academic Press, New York (1957)Google Scholar
23. Naito, K., Tsuji, T., Ohuchi, K., Yahata, T., Yamashita, T., Tagawa, H., J. Nucl. Mater. 95 (1980) 181–184.Google Scholar