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Oxygen Ion Conductivity in a New Class of Layered Bismuth Oxide Compounds

Published online by Cambridge University Press:  25 February 2011

Julie K. Thomas ,
Mairin E. Anderson ,
Wendy E. Krause  and
Hansconrad Zur Loye
Julie K. Thomas
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, MA 02139.
Mairin E. Anderson
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, MA 02139.
Wendy E. Krause
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, MA 02139.
Hansconrad Zur Loye
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, MA 02139.
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Abstract

Compounds that consist of intergrowths between the Aurivillius phase Bi4Ti3O12 and brownmillerite-like slabs of BaMO2.5were synthesized and their oxygen ion conductivities investigated. Both BaBi4Ti3ScO14.5 and BaBi4Ti3InO14.5 display a discontinuity in their Arrhenius plots that appears to be caused by an oxygen vacancy order-disorder transition. Conductivity data for two Aurivillius phases BaBi4Ti4O15 and BaBi2Nb2O9 are included for comparison.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 293: Symposium U – Solid State Ionics III , 1992 , 295
Copyright
Copyright © Materials Research Society 1993

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