Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-17T20:17:19.192Z Has data issue: false hasContentIssue false

Oxidation Behavior of Advanced Intermetallic Compounds

Published online by Cambridge University Press:  26 February 2011

Douglas W. Mckee
Affiliation:
General Electric Company, Research and Development Center, P.O. Box 8, Schenectady, NY 12301.
Robert L. Fleischer
Affiliation:
General Electric Company, Research and Development Center, P.O. Box 8, Schenectady, NY 12301.
Get access

Abstract

The oxidation behavior of a number of ordered high melting point intermetallic materials has been studied in flowing air in the temperature range 1000 to 1500°C. The alloys were selected for acceptable toughness and ductility at temperatures above 1000°C. Included were ruthenium aluminides, chromium silicide and compounds of iridium and ruthenium with elements such as titanium, tantalum, nickel, iron, cobalt, silicon, vanadium and rhenium. In general, alloys containing the metals iron, cobalt and nickel, and also titanium and tantalum, oxidized rapidly at 1000°C and above. Oxidation-resistant materials were those capable of forming scales of chromia/silica or alumina. Intermetallic compounds of chromium and ruthenium formed volatile oxides above 1200°C, but binary compounds of these elements with silicon and aluminum were highly oxidation resistant at lower temperatures.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Taub, A.I. and Fleischer, R.L., Science 243, 616 (1989).CrossRefGoogle Scholar
2. Anton, D.L., Shah, D.M., Duhl, D.N. and Giamei, A.F., J.of Metals p.12,Sept.(1989)CrossRefGoogle Scholar
3. Chang, Y.A., Trans. AIME 242(8), 1509 (1968).Google Scholar
4. Massalski, T., Binary Alloy Phase Diagrams, ASM, Metals Park OH (1986).Google Scholar
5. Fleischer, R.L. and Zabala, R.J., Met.Trans. 21A, 1951 (1990).Google Scholar
6. Fleischer, R.L., Field, R.D., Denike, K.K. and Zabala, R.J., to be published.Google Scholar
7. Fleischer, R.L., Field, R.D. and Briant, C.L., to be published.Google Scholar
8. Fleischer, R.L., General Electric Report 90CRD095.Google Scholar
9. Grabke, H.J. and Brumm, M. in Oxidation of High-Temperature Intermetallics, TMS Pub. p.245 (1988).Google Scholar
10. Kofstad, P., High Temperature Corrosion (Elsevier 1988), p.390.Google Scholar
11. Alcock, C.B., Proc. Roy.Soc.(London), A254, 551 (1959).Google Scholar
12. Chou, T.C., J. Mater. Res. 5(2), 378 (1990).CrossRefGoogle Scholar