Hostname: page-component-7bb8b95d7b-lvwk9 Total loading time: 0 Render date: 2024-10-02T22:15:28.659Z Has data issue: false hasContentIssue false

Origin and Incorporation Mechanism for Oxygen Contaminants in a-Si:H and μc-Si:H Films Prepared by the Very High Frequency (70 MHz) Glow Discharge Technique

Published online by Cambridge University Press:  15 February 2011

U. Kroll
Affiliation:
Institut de Microtechnique, Université de NeuchÂtel, CH-2000 NeuchÂtel, Switzerland
J. Meier
Affiliation:
Institut de Microtechnique, Université de NeuchÂtel, CH-2000 NeuchÂtel, Switzerland
H. Keppner
Affiliation:
Institut de Microtechnique, Université de NeuchÂtel, CH-2000 NeuchÂtel, Switzerland
S. D. Littlewood
Affiliation:
Institut de Microtechnique, Université de NeuchÂtel, CH-2000 NeuchÂtel, Switzerland
I. E. Kelly
Affiliation:
Institut de Microtechnique, Université de NeuchÂtel, CH-2000 NeuchÂtel, Switzerland
P. Giannoulès
Affiliation:
Institut de Microtechnique, Université de NeuchÂtel, CH-2000 NeuchÂtel, Switzerland
A. Shah
Affiliation:
Institut de Microtechnique, Université de NeuchÂtel, CH-2000 NeuchÂtel, Switzerland
Get access

Abstract

The effect of plasma power, reactor outgassing rate and feed gas purity on the oxygen content of amorphous silicon (a-Si:H) and microcrystalline silicon (μc-Si:H) layers, prepared by the VHF (70 MHz) glow discharge technique has been investigated. The oxygen concentration in the films was measured by Secondary Ion Mass Spectrometry. The gas purity could be optionally enhanced by the application of a getter-based gas purifier mounted in the gas pipe just before the reactor. The purifier reduces the oxygen contaminants in the feed gas to levels in the ppb range. It was found that oxygen incorporation was enhanced at lower deposition rates. The deposition rate dependence of the oxygen incorporation is in excellent agreement with the proposed incorporation mechanism. Furthermore, the reactor outgassing rate and the purity of the feed gas itself were identified as the main contamination sources for the oxygen contaminants in the deposited a-Si:H films as well as in μc-Si:H films : e.g. at outgassing rates in the range of 10−6 mbar 1 s−1, at least around half of the oxygen detected in both a-Si:H and in the μc-Si:H layers originates from the feed gas if the latter is unpurified. By combining reduced outgassing rates and the use of purified feed gas, a-Si:H and μc-Si:H films with an oxygen concentration of 5×1017cm−3 and 2×1018cm−3, respectively, were deposited. These values both represent the lowest concentrations of oxygen contaminants reported to date for these kinds of materials.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Nakata, M., Wagner, S. and Peterson, T.M., J. Non-Cryst. Solids, 164–166, 179 (1993).Google Scholar
2. Hishikawa, Y., Ninomiya, K., Maruyama, E., Kuroda, S., Terakawa, A., Sayama, K., Tarui, H., Sasaki, M., Tsuda, S. and Nakano, S., Proc. of the 1st WCPEC, (1994), to be published.Google Scholar
3. Morimoto, A., Matsumoto, M., Kumeda, M. and Shimizu, T., Jpn. J. Appl. Phys., 29, L1747 (1990).Google Scholar
4. Morimoto, A., Matsumoto, M., Yoshita, M., Kumeda, M. and Shimizu, T., Appl. Phys. Lett., 59, 2130 (1991).Google Scholar
5. Kroll, U., Meier, J., Goetz, M., Howling, A., Dorier, J.-L., Dutta, J., Shah, A. and Hollenstein, Ch., J. Non-Cryst. Solids, 164–166, 59 (1993).Google Scholar
6. Flückiger, R., Meier, J., Keppner, H., Kroll, U., Shah, A., Greim, O., Morris, M., Pohl, J., Hapke, P. and Carius, R., Proc. of the 11th EC PV Solar Energy Conf., 617 (1992).Google Scholar
7. Briesacher, J.L., Nakamura, N. and Ohmi, T., Electrochem, J.. Soc, 138, 3717 (1991).Google Scholar
8. Boucheron, D., Jehanno, P., Simondet, F., Succi, M. and Solcia, C., Microcontamination, 9, 29 (1991).Google Scholar
9. Howling, A., Dorier, J.-L., Hollenstein, Ch., Kroll, U., Finger, F., J. Vac. Sci. Technol. A, 10, 1080 (1992).Google Scholar