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Organophosphorus-Based Organic / Inorganic Hybrids

Published online by Cambridge University Press:  01 February 2011

André Vioux ,
P. Hubert Mutin ,
Jean Le Bideau  and
Dominique Leclercq
André Vioux
Affiliation:
UMR CNRS 5637, Université de Montpellier 2, case 007, Place E. Bataillon, F34095 Montpellier Cedex 5, FRANCE
P. Hubert Mutin
Affiliation:
UMR CNRS 5637, Université de Montpellier 2, case 007, Place E. Bataillon, F34095 Montpellier Cedex 5, FRANCE
Jean Le Bideau
Affiliation:
UMR CNRS 5637, Université de Montpellier 2, case 007, Place E. Bataillon, F34095 Montpellier Cedex 5, FRANCE
Dominique Leclercq
Affiliation:
UMR CNRS 5637, Université de Montpellier 2, case 007, Place E. Bataillon, F34095 Montpellier Cedex 5, FRANCE
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Abstract

This paper is a concise review of some recent works which highlights the interest of phosphonate groups RP (O)32- in the field of organic/inorganic hybrid materials, as a general alternative to silicon coupling agents in anchoring of an organic group to an inorganic support or within an inorganic network. Examples, focused on metals of groups 4 and 13, illustrate various synthetic routes, from the hydrothermal synthesis of two- or three-dimensional metal phosphonates, to the introduction of organic moieties into oxide matrices by sol-gel processing, without excluding the grafting of metal oxide surfaces.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 628: Symposium CC – Hybrid Organic/Inorganic Materials , 2000 , CC1.4
Copyright
Copyright © Materials Research Society 2000

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