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Organoclay Nanoplatelets at the Air/water Interface

Published online by Cambridge University Press:  21 March 2011

Yimin Zhang
Affiliation:
Materials Research Science and Engineering Center, Department of Materials Science and Engineering, State University of New York at Stony Brook, New York 11794-2275
Henry White
Affiliation:
Materials Research Science and Engineering Center, Department of Materials Science and Engineering, State University of New York at Stony Brook, New York 11794-2275
Miriam H. Rafailovich
Affiliation:
Materials Research Science and Engineering Center, Department of Materials Science and Engineering, State University of New York at Stony Brook, New York 11794-2275
Jonathan Sokolov
Affiliation:
Materials Research Science and Engineering Center, Department of Materials Science and Engineering, State University of New York at Stony Brook, New York 11794-2275
Dennis Peiffer
Affiliation:
Exxon-Mobil Research and Engineering Co., Annandale, NJ 08801
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Abstract

We have demonstrated that films of single clay platelets can be produced by the Langmuir technique where a solution of organoclay particles dissolved in xylene was spread at the air water interface. The total thickness of the layer was found to be 21 ± 3Å which is in good agreement with previous X-ray diffraction data. Scanning probe microscopy showed the individual platelets to be rectangular in shape with an aspect ratio in excess of 100 to 1 and of uniform organic surfactant coverage.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

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