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Organic-Inorganic Crystals for Optical Devices

Published online by Cambridge University Press:  10 February 2011

A. Ibanez ,
J. Zaccaro ,
P. L. Baldeck  and
R. Masse
A. Ibanez
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France
J. Zaccaro
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France
P. L. Baldeck
Affiliation:
Laboratoire de Spectrométrie Physique, Université Joseph Fourier, BP 87, 38402 Saint Martin d'Hères Cedex, France
R. Masse
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France
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Abstract

Two routes of crystal engineering and elaboration of optical materials are described. The former applied to the design of organic-inorganic crystals for quadratic nonlinear optics is supported by a strategy of deliberately engineered noncentrosymmetric structures built-up from herringbone motifs of 2-amino-5-nitropyridinium chromophore. The original crystal growth of a solid solution of a member of this family is presented and discussed. The latter is a simple and generic elaboration of stable organic nanocrystals embedded in sol-gel matrices. Several molecules and characterization techniques have been involved to demonstrate the validity of this preparation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 245
Copyright
Copyright © Materials Research Society 1998

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