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Organic, Organometallic and Polymeric Materials with Nonlinear Optical Properties

Published online by Cambridge University Press:  21 February 2011

S. R. Marder ,
J. W. Perry ,
W. P. Schaefer ,
E. J. Ginsburg ,
C. B. Gorman  and
R. H. Grubbs
S. R. Marder
Affiliation:
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109
J. W. Perry
Affiliation:
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109
W. P. Schaefer
Affiliation:
Division of Chemistry and Chemical Engineering,[1]California Institute of Technology, Pasadena, CA 91125
E. J. Ginsburg
Affiliation:
Division of Chemistry and Chemical Engineering,[1]California Institute of Technology, Pasadena, CA 91125
C. B. Gorman
Affiliation:
Division of Chemistry and Chemical Engineering,[1]California Institute of Technology, Pasadena, CA 91125
R. H. Grubbs
Affiliation:
Division of Chemistry and Chemical Engineering,[1]California Institute of Technology, Pasadena, CA 91125
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Abstract

New approaches to both second-order and third-order nonlinear optical materials are presented. A series of organometallic and organic salts, in which the cation has been designed to have a large molecular hyperpolarizability, has been prepared and the SHG efficiencies were measured. Partially substituted derivatives of polyacetylene are synthesized via the ring-opening metathesis polymerization (ROMP) of cyclooctatetraene (COT) and its derivatives. Certain poly-COT derivatives afford soluble, highly conjugated polyacetylenes. These materials exhibit large third-order optical nonlinearities and low scattering losses.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 175: Symposium S – Multifunctional Materials , 1989 , 101
Copyright
Copyright © Materials Research Society 1990

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References

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