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Organic Catalysts in the Silica Sol-Gel System

Published online by Cambridge University Press:  28 February 2011

T.A. Gallo
Affiliation:
Akzo Chemicals Inc., ARLDF, Livingstone Avenue, Dobbs Ferry, NY 10522.
B.L. Simms
Affiliation:
Akzo Chemicals Inc., ARLDF, Livingstone Avenue, Dobbs Ferry, NY 10522.
V.T. Brice
Affiliation:
Akzo Chemicals Inc., ARLDF, Livingstone Avenue, Dobbs Ferry, NY 10522.
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Abstract

Ethyl silicate-derived silica gels were synthesized with organic acid and base hydrolysis catalysts. The nature of the organic catalyst was found to strongly affect dry gel structure and carbon content. No consistent relationship between dry gel structure and water content of the calcined gels was identified.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Nogami, M. and Moriya, Y., J. Non-Cryst. Sol., 37, 191 (1980).Google Scholar
2. Klein, L.C., Annu. Rev. Mater. Sci., 15, 227 (1985).Google Scholar
3. Scherer, G.W., Brinker, C.J., Roth, E.P., J. Non-Cryst. Sol., 72, 369(1985).Google Scholar
4. Termin, E., Lenz, A., and Bleh, O., U.S. Patent No.4 006 175 (February 1, 1977).Google Scholar
5. Williams, J.P.,Su, Y., Strzegowski, W.R., Butler, B.L., Hoover, H.L., and Altemose, V.O.., Am. Ceram. Soc. Bull.,55,524 (1976).Google Scholar
6. Pope, E.J.A. and Mackenzie, J.D., J. Non-Cryst. Sol., 87, 185 (1986).Google Scholar
7. Artaki, I., Zerda, T.W. and Jonas, J., J. Non-Cryst. Sol., 81, 381 (1986).Google Scholar
8. Iler, Ralph K.,The Chemistry Of Silica, (John Wiley & Sons, Inc. 1979), p. 59.Google Scholar