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Optical Evidence of Reduction of Radiative Defects in Diamond Films Grown by Acetylene-Oxygen Flames

Published online by Cambridge University Press:  25 February 2011

J. A. Freitas Jr
Affiliation:
Naval Research Laboratory, Washington, DC 20375–5000
U. Strom
Affiliation:
Naval Research Laboratory, Washington, DC 20375–5000
K. Doverspike
Affiliation:
Naval Research Laboratory, Washington, DC 20375–5000
C. M. Marks
Affiliation:
Naval Research Laboratory, Washington, DC 20375–5000
K. A. Snail
Affiliation:
Naval Research Laboratory, Washington, DC 20375–5000
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Abstract

Raman scattering and photoluminescence spectroscopies have been used to characterize polycrystalline diamond films deposited on molybdenum substrates by laminar and turbulent premixed oxygen-acetylene flames in air. Samples deposited under laminar flame conditions are characterized by a high degree of incorporation of nitrogen-vacancy complexes. However, samples deposited with a turbulent flame show a significant decrease in the concentration of these defects and a reduction of the amorphous carbon film component.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Hanssen, L. M., Carrington, W. A., Butler, J. E., and Snail, K. A., Mat. Lett., 7, 289 (1988).Google Scholar
2. Hanssen, L. M., Snail, K. A., Carrington, W. A., Buttler, J. E., Kellog, S., and Oakes, D. B., Thin Solid Films, 196, 271 (1991).Google Scholar
3. Freitas, J. A. Jr, Butler, J. E. and Strom, U., J. Mater. Res., 5, 2502 (1990).Google Scholar
4. Freitas, J. A. Jr, Strom, U., Butler, J. E., and Snail, K. A. Proc. of The 2nd Intl. Conf. on New Diamond Science and Technology (MRS, Washington, DC September 1990), p. 723.Google Scholar
5. Snail, K. A., Craigie, C. J., Vardinam, R. G., Marks, C. M., and Freitas, J. A. Jr, Proc. of The 2nd Intl. Symp. on Diamond Materials (ECS - 2), Washinton, DC May 1991, vol. 91–8, p. 91.Google Scholar
6. Manning, D. C., Atomic Absorption Newsletter, 7, 44 (1968)).Google Scholar
7. Walker, J., Rep. Prog. Phys. 42, 1605 (1979).Google Scholar
8. Davies, G., Rep. Prog. Phys., 44, 787 (1981).Google Scholar
9. Collins, A. T. and Robertson, S.H., J. Mat. Sci. Lett. 4, 2223 (1971).Google Scholar
10. Sato, Y., Hata, C., Ando, T. and Kamo, M., Proc. of The 2nd Intl. Conf. on New Diamond Science and Technology (MRS, Washington, DC September 1990), p. 537.Google Scholar