Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-25T15:22:51.424Z Has data issue: false hasContentIssue false
  • English
  • Français

One and Two-dimensional Semiconducting Nanostructures Self-assembly of Conjugated Oligomers

Published online by Cambridge University Press:  10 February 2011

Ph. Leclère ,
M. Surin ,
P. Jonkheijm ,
O. Henze ,
A.P.H.J. Schenning ,
F. Biscarini ,
A.C. Grimsdale ,
W.J. Feast ,
E.W. Meijer  and
K. Müllen
...Show all authors
Ph. Leclère
Affiliation:
Service de Chimie des Matériaux Nouveaux, Université de Mons-Hainaut/Materia Nova, Place du Parc, 20, B-7000 Mons (Belgium). Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, NL-5600 MB Eindhoven (The Netherlands).
M. Surin
Affiliation:
Service de Chimie des Matériaux Nouveaux, Université de Mons-Hainaut/Materia Nova, Place du Parc, 20, B-7000 Mons (Belgium).
P. Jonkheijm
Affiliation:
Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, NL-5600 MB Eindhoven (The Netherlands).
O. Henze
Affiliation:
IRC in Polymer Science and Technology, Durham University, South Road, Durham DH1 3LE, (United Kingdom).
A.P.H.J. Schenning
Affiliation:
Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, NL-5600 MB Eindhoven (The Netherlands).
F. Biscarini
Affiliation:
Consiglio Nazionale delle Richerche (CNR) – Istituto per lo Studio dei Materiali Nanostrutturati (ISMN), Via P. Gobetti 101, I-40129 Bologna (Italy).
A.C. Grimsdale
Affiliation:
Max-Planck Institut für Polymerforschung(MPI-P), Mainz (Germany).
W.J. Feast
Affiliation:
IRC in Polymer Science and Technology, Durham University, South Road, Durham DH1 3LE, (United Kingdom).
E.W. Meijer
Affiliation:
Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, NL-5600 MB Eindhoven (The Netherlands).
K. Müllen
Affiliation:
Max-Planck Institut für Polymerforschung(MPI-P), Mainz (Germany).
J.L. Brédas
Affiliation:
Department of Chemistry, University of Arizona, Tucson, AZ (USA).
R. Lazzaroni
Affiliation:
Service de Chimie des Matériaux Nouveaux, Université de Mons-Hainaut/Materia Nova, Place du Parc, 20, B-7000 Mons (Belgium).
Get access

Abstract

The properties of organic electronic materials in the solid-state are determined not only by those of individual molecules but also by those of ensembles of molecules. The ability to control the architectures of these ensembles is thus essential for optimising the properties of conjugated materials for use in electronic devices (light emitting diodes, field effect transistors, solar cells,…) and is primordial for potential technological applications in nanoelectronics.

Here, we report on the observation by atomic force microscopy (AFM) of 1D and 2D nanoscale architectures obtained in the solid-state from solutions of molecularly-dissolved conjugated block copolymers or oligomers, and demonstrate that the conjugated molecules can organize onto a surface over lengthscales from nanometers to several microns, forming semiconducting fibrils by π-stacking processes.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 775: Symposium P – Self-Assembled Nanostructured Materials , 2003 , P8.7
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1]. Friend, R.H., Gymer, R.W., Holmes, A.B., Burroughes, J.H., Marks, R.N., Taliani, C., Bradley, D.C.C., Santos, D.A. dos, Brédas, J.L., Logdlund, M., Salaneck, W.R., Nature, 397, 121 (1999).Google Scholar
[2]. Martin, R. E., Diederich, F., Angew. Chem. Int. Ed., 38, 1350 (1999).Google Scholar
[3]. Meijer, E.W., Schenning, A.P.H.J., Nature, 419, 353 (2002).Google Scholar
[4]. Marsitzky, D., Klapper, M., Müllen, K., Macromolecules, 32, 8685 (1999); S. Setayesh, D. Marsitzky, K. Müllen, Macromolecules, 33, 2016 (2000); S. Setayesh, A.C. Grimsdale, T. Weil, V. Enkelman, K. Müllen, F. Meghdadi, E.J.W. List, G. Leising, J. Am. Chem. Soc., 123, 946 (2001).Google Scholar
[5]. Leclère, Ph., Calderone, A., Marsitzky, D., Francke, V., Geerts, Y., Müllen, K., Brédas, J.L., Lazzaroni, R., Adv. Mater., 12, 1042 (2000); Ph. Leclère, E. Hennebicq, A. Calderone, P. Brocorens, A.C. Grimsdale, K. Müllen, J.L. Brédas, and R. Lazzaroni, Progr. Polym. Sci., 28, 55 (2003); A.C. Grimsdale, Ph. Leclère, R. Lazzaroni, J.D. Mackenzie, C. Murphy, S. Setayesh, C. Silva, R.H. Friend, and K. Müllen, Adv. Funct. Mater., 12, 729 (2002).Google Scholar
[6]. Surin, M., Leclère, Ph., Marzistsky, D., Grimsdale, A.C., Müllen, K., and Lazzaroni, R., to be published.Google Scholar
[7]. Kilbinger, A.F.M., Schenning, A.P.H.J., Goldoni, F., Feast, W.J., Meijer, E.W., J. Am. Chem. Soc., 122, 1280 (2000); A.P.H.J. Schenning, A.F.M. Kilbinger, F. Biscarini, M. Cavallini, H.J. Cooper, P.J. Derrick, W.J. Feast, R. Lazzaroni, Ph. Leclère, L.A. McDonell, E.W. Meijer, S.C.J. Meskers, J. Am. Chem. Soc., 124, 1269 (2002).Google Scholar
[8]. Jonkheijm, P., Fransen, M., Schenning, A.P.H.J., Meijer, E.W., J. Chem. Soc. Perkin. Trans 2, 1280 (2001).Google Scholar
[9]. Schenning, A.P.H.J., El-ghayoury, A., Peeters, E., Meijer, E.W., Synth. Met., 121, 1253 (2001).Google Scholar
[10]. Henze, O., Jonkheijm, P., Schenning, A.P.H.J., Meijer, E.W., Feast, W.J., to be published.Google Scholar
[11]. Thomas, B.N., Lindemann, C.M., and Clark, N.A., Phys. Rev. E, 59, 3040 (1999).Google Scholar
[12]. Bouman, M.M., Meijer, E.W., Adv. Mater. 1995, 7, 385; G. Bidan, S. Guillerez, V. Sorokin, Adv. Mater. 1996, 8, 157.Google Scholar