Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-25T18:06:12.893Z Has data issue: false hasContentIssue false
  • English
  • Français

The Observations of Paramagnetic Centers in Tellurite Glasses

Published online by Cambridge University Press:  16 February 2011

J.D. Prohaska ,
J. Li ,
S. Kannan ,
E. Snitzer ,
J.S. Wang  and
R.H. Bartram
J.D. Prohaska
Affiliation:
Dept. of Ceramics Science and Engineering; Rutgers University, Piscataway, NJ
J. Li
Affiliation:
Dept. of Ceramics Science and Engineering; Rutgers University, Piscataway, NJ
S. Kannan
Affiliation:
Dept. of Ceramics Science and Engineering; Rutgers University, Piscataway, NJ
E. Snitzer
Affiliation:
Dept. of Ceramics Science and Engineering; Rutgers University, Piscataway, NJ
J.S. Wang
Affiliation:
AT&T Bell Laboratories, Holmdel, NJ
R.H. Bartram
Affiliation:
Dept. of Physics and Institute of Materials Science; University of Connecticut, Storrs, CT
Get access

Abstract

This is the first report of ESR observations of three distinct paramagnetic centers in TeO29 glasses. One center is intrinsic to the glass and the other two are induced by KrFexcimer-laser radiation. The intrinsic center with a broad ESR spectrum is tentatively identified as an oxygen-associated hole center. One radiation-induced center fades slowly at room temperature; its proposed structure is that of an electron trapped in a diffuse orbital associated with a modifier ion. The other radiation-induced center is stable at room temperature and corresponds to the Vo· center observed in crystalline paratellurite.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 373: Symposium Y – Microstructure of Irradiated Materials , 1994 , 443
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Wang, J.S., Vogel, E. and Snitzer, E., Optical Materials, accepted for publication (1994).Google Scholar
2. Wang, J.S., Machewirth, D.P., Wu, F., Vogel, E. and Snitzer, E., Opt. Let. 19(18), 1448 (1994).Google Scholar
3. Prohaska, J.D., Garton, R.T., Wang, J.S., Wu, F., and Snitzer, E., paper number PD2.2, (Conference Proceeding of the Lasees, and Electro Optics Symposium, Boston, MA, 1994) p.133.Google Scholar
4. Wyckoff, R.W.G., Crystal Structures Vol. I, 2nd. ed. (Interscience, New York, 1963).Google Scholar
5. Beyer, H., Z. Krist. 102, 13 (1939).Google Scholar
6. Lindgvist, O., Acta Chem. Scand 22, 977 (1968).Google Scholar
7. Brady, G.W., J. Chem. Phys. 27, 300 (1957).Google Scholar
8. Neov, S., Kozhukharov, V., Gerassimova, I., Krezhov, K., and Sidzhimov, B., J. Phys. C12, 2475 (1979).Google Scholar
9. Neov, S., Gerassimova, I., Krezhov, K., Sidzhimov, B., and Kozhukharov, V., Phys. Stat. Sol. (a) 47, 743 (1978).Google Scholar
10. Neov, S., Gerassimova, I., Kozhukharov, V., and Marinov, M., J. Mat. Sci. 15, 1153 (1980).Google Scholar
11. Dimitriev, Y. and Gateff, E., Kashchieva, E. and Dimitrov, V., (Proc. 1lth Int. Congress on Glass, 1, Prague, 1977) p.159.Google Scholar
12. Dimitriev, Y. and Dimitrov, V., Mat. Res. bull. 13, 1071 (1978).Google Scholar
13. Johnson, P.A.V., Wright, A.C., Yarker, C.A., and Sinclair, R.N., J. Non-Cryst. Solids, 81, 163 (1986).Google Scholar
14. Muncaster, R. and Parke, S., J. Non-Cryst. Solids 24, 399 (1977).Google Scholar
15. Watterich, A., Bartram, R.H., Gilliam, O. R., Kappers, L. A., and Edwards, G. J., Phys. Rev. 32(4), 2533 (1985).Google Scholar
16. Griscom, D.L., Glass Science and Technology Vol. 4b, ed. Uhlmann, D.R. and Kreidl, N. (Academic Press, Boston) 151 (1990).Google Scholar