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Observation of Long-Range Orientational Ordering in Metal Films Evaporated at Oblique Incidence onto Glass

Published online by Cambridge University Press:  14 March 2011

David L. Everitt
Affiliation:
Department of Physics, University of California at Davis, Davis, California 95616
X. D. Zhu*
Affiliation:
Department of Physics, University of California at Davis, Davis, California 95616
William J. Miller
Affiliation:
Department of Chemical Engineering and Materials Science, University of California at Davis, Davis, California 95616
Nicholas L. Abbott
Affiliation:
Department of Chemical Engineering, University of Wisconsin, Madison, Wisconsin 53706
*
*to whom correspondence should be made ([email protected])
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Abstract

We studied long-range orientational ordering in polycrystalline Au films (10 nm - 30 nm) that are evaporated at oblique incidence onto a glass substrate at room temperature. By measuring the averaged optical second-harmonic response from the films over a 6-mm diameter region, we observed a transition from the expected in-plane mirror symmetry at 10 nm to a surprising three-fold in-plane rotational symmetry at 30 nm. X-ray pole figure analysis performed on these films showed the strong <111> fiber texture typical of fcc films, but with a restricted, three-fold symmetric, distribution of crystallite orientations about the fiber axis.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

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