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NTO Decomposition Studies

Published online by Cambridge University Press:  10 February 2011

J. C. Oxley ,
J. L. Smith ,
K. E. Yeager ,
E. Rogers  and
X. X. Dong
J. C. Oxley
Affiliation:
University of Rhode Island; GRC, P.O. Box 984, West Kingston, RI 02892
J. L. Smith
Affiliation:
University of Rhode Island; GRC, P.O. Box 984, West Kingston, RI 02892
K. E. Yeager
Affiliation:
University of Rhode Island; GRC, P.O. Box 984, West Kingston, RI 02892
E. Rogers
Affiliation:
University of Rhode Island; GRC, P.O. Box 984, West Kingston, RI 02892
X. X. Dong
Affiliation:
University of Rhode Island; GRC, P.O. Box 984, West Kingston, RI 02892
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Abstract

To examine the thermal decomposition of 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO) in detail, isotopic labeling studies were undertaken. NTO samples labeled with 15N in three different locations [ N(l) and N(2), N(4), and N (6)] were prepared.1 Upon thermolysis, the majority of the NTO condensed-phase product was a brown, insoluble residue, but small quantities of 2,4,-dihydro-3H- 1,2,4-triazol-3-one (TO) and triazole were detected.2 Gases comprised the remainder of the NTO decomposition products. The analysis of these gases is reported herein along with mechanistic implications of these observations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 418: Symposium GG – Decomposition, Combustion, and Detonation Chemistry of Energetic Materials , 1995 , 135
Copyright
Copyright © Materials Research Society 1996

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References

1. Oxley, J.; Smith, J.; Yeager, K.; Coburn, M.; Ott, D. J. Energetic Materials 1995, 13(1&2), 93–105.Google Scholar
2. Oxley, J.C.; Smith, J.L.; Zhou, Z.; McKenney, R-L. J.Phys.Chem, 1995, 99(25), 10383–10391.Google Scholar
3. Oxley, J.C.; Smith, J.; Yeager, K; Roger, E.; Dong, X.X. submitted J.Phys.Chem.Google Scholar
4. Menapace, J.A.; Marlin, J.; Bruss, D.; Dascher, R. J. Phys. Chem., 1991, 95, 5509–5517.Google Scholar
5. Beard, B.C.; Sharma, J. J. Energetic Materials, 1989, 7(3),181.Google Scholar
6. Ostmark, H., “Thermal Decomposition of NTO” FOA Rep. D-201782.3, Nov. 1991.Google Scholar
7. Rothgery, E.F.; Audette, D.E.; Wedlich, R.; Csejka, D. Thermochim Acta, 1991, 185, 235.Google Scholar
8. Botcher, T.R.; Beardali, D.J.; Wight, C.A. submitted J.Phys.Chem.Google Scholar
9. “Supplement F: The Chemistry of Amino, Nitroso, and Nitro Compounds and Their Derivatives” Part 1; Patai, S. Ed. Wiley, NY, 1982 p146.Google Scholar
10. Janssen, J.W.A.M.; Habraken, C.L.; Louw, R. J.Org.Chem., 1976, 41(10), 1758–1762.Google Scholar
11. Williams, G.K.; Palopoli, S.F.; Brill, T.B. Combust. Flame, 1994, 98, 197.Google Scholar