Hostname: page-component-586b7cd67f-vdxz6 Total loading time: 0 Render date: 2024-11-26T15:32:47.823Z Has data issue: false hasContentIssue false

Novel Strategy for Antifouling Paints with Zero Endocrine Disrupting Chemical (EDC) Elution based on Interpenetrating Polymer Networks (IPNs)

Published online by Cambridge University Press:  01 February 2011

Masanobu Naito
Affiliation:
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan
Takashi Nakai
Affiliation:
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan
Takuma Kawabe
Affiliation:
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan
Kenji Mori
Affiliation:
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan
Daisuke Furuta
Affiliation:
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan
Yukio Imanishi
Affiliation:
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan
Michiya Fujiki
Affiliation:
Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan
Get access

Abstract

Environmentally friendly organic-inorganic hybrid materials with repellent activity against marine fouling organisms have been developed using interpenetrating polymer networks (IPNs), composed of a three-dimensional silica matrix of tetraethoxysilane (TEOS) and chain-like polymers, such as poly(methylmethacrylate) (PMMA) and poly(vinylacetate) (PVAc). The repellent activity of the IPNs reached a maximum of approximately 90% relative to that of tetrabutyl tin oxide (TBTO). Simple bioassays using blue mussels and algae were used to screen out the adequate proportions of those components.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Omae, I., Chem. Rev., 103, 3431 (2003).Google Scholar
2 Mera, A. E., Wynne, K. J., U. S. Patent 62665515 (2001).Google Scholar
3 Ina, K., Takasawa, R., Yagi, A., Yamashita, N., Eto, H., and Sakata, K., Agric. Biol. Chem., 53, 3319 (1989).Google Scholar
4 Yu, M., Hwang, J., and Deming, T. J., J. Am. Chem. Soc., 121, 5825 (1999).Google Scholar
5(a) Coyne, K. J., Qin, X.-X., and Waite, J. H., Science, 277, 1830 (1997).Google Scholar
(b) Waite, J. H. and Tanzer, M. L., Science, 212, 1038 (1981).Google Scholar
6 Bourlinos, A. B., Karakassides, M. A., and Petridis, D.,J. Phys. Chem. B, 104, 4375 (2000).Google Scholar
7 Vallet-Regi, M., Salinas, A. J., Ramirez-Castellanos, J., and Gonzalez-Calbet, J. M., Chem. Mater. ASAP article (2005).Google Scholar