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Nonlinear Optical Studies of Mixed π-Conjugated Polymer Multilayers by Second Harmonic Generation

Published online by Cambridge University Press:  25 February 2011

H. Koezuka ,
T. Kurata ,
A. Tsumura  and
H. Fuchigami
H. Koezuka
Affiliation:
Mitsubishi Electric Corporation, Materials & Electronic Devices Laboratory, 1–1 Tsukaguchi Honmachi 8-Chome, Amagasaki, Hyogo 661, Japan
T. Kurata
Affiliation:
Mitsubishi Electric Corporation, Materials & Electronic Devices Laboratory, 1–1 Tsukaguchi Honmachi 8-Chome, Amagasaki, Hyogo 661, Japan
A. Tsumura
Affiliation:
Mitsubishi Electric Corporation, Materials & Electronic Devices Laboratory, 1–1 Tsukaguchi Honmachi 8-Chome, Amagasaki, Hyogo 661, Japan
H. Fuchigami
Affiliation:
Mitsubishi Electric Corporation, Materials & Electronic Devices Laboratory, 1–1 Tsukaguchi Honmachi 8-Chome, Amagasaki, Hyogo 661, Japan
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Abstract

The structures of the mixed LB monolayers, composed of two different kinds of π-conjugated system, poly(3-hexylthiophene) (PHT) and pentacosa-10, 12-diynoic acid (DA), have been investigated mainly by a second harmonic generation (SHG) Maker fringe method. The mixed LB films partly contain a double-layered structure consisting of PHT and DA. The second harmonic radiation has been produced from slightly twisted PHT in the double layer. Both UV-polymerization of DA and successive heat-treatments enhanced the SHG intensities. The enhancement of the SHG intensities has been elucidated by the enlargement of the PHT twisting and the interaction between PHT and a newly formed π-conjugated system.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 173: Symposium Q – Advanced Organic Solid State Materials , 1989 , 691
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

[1]See, for example, Nonlinear Optical Properties of Polymers, edited by Heeger, A. J., Orenstein, J. and Ulrich, D. R. (MRS, Pittsburgh, 1988).Google Scholar
[2] Khanarian, G., Thin Solid Films, 152, 265 (1987).CrossRefGoogle Scholar
[3] Sugimoto, R., Takeda, S., Gu, H. B. and Yoshino, K., Chem. Express, 1, 635 (1986).Google Scholar
[4] Girling, I. R., Cade, N. A., Kolinsky, P. V., Eaels, J. D., Cross, G. H. and Peterson, I. R., Thin Sold Films, 132, 101 (1985).Google Scholar
[5] Ledoux, I., Josse, D.. Fremaux, P., Piel, J.-P., Post, G., Zyss, J., McLean, T., Hann, R. A., Gordon, P. F. and Allen, S., Thin Solid Films, 160, 217 (1988).CrossRefGoogle Scholar
[6] Love, P., Sugimoto, R., Yoshino, K., Japan J. Appl. Phys. 27, L1562 (1988).Google Scholar
[7] Ogawa, K., Tamura, H., Hatada, M. and Ishihara, T., Langmuir, 4, 903 (1988).Google Scholar
[8] Heinz, P. F., Tom, H. W. K. and Shen, Y. R., Phys. Rev. A28, 1883 (1983).Google Scholar