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Nonaqueous Viscous Electrolytes for Growth of Anodic Titania Nanotubes

Published online by Cambridge University Press:  01 February 2011

Jan M. Macak
Affiliation:
[email protected], University of Erlangen, D. of Materials Science, Martensstr. 7, Erlangen, 91058, Germany
Sergiu P. Albu
Affiliation:
[email protected], University of Erlangen, Materials Science, Erlangen, 91058, Germany
Patrik Schmuki
Affiliation:
[email protected], University of Erlangen, Materials Science, Erlangen, 91058, Germany
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Abstract

The present work compares two different organic electrolytes (glycerol and ethylene glycol) for the growth of self-organized TiO2 nanotubes by anodic oxidation of Ti. In both electrolytes these self-organized layers of TiO2 nanotubes can be grown to considerable thickness (several 10 μm). It is found that except for the detailed electrochemical conditions also the water content has a dramatic influence on the tube dimensions, mainly length and tube morphology. The best result in terms of length is achieved in “water-free” electrolytes.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

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References

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