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Nmr Studies of Polymer Electrolytes

Published online by Cambridge University Press:  28 February 2011

S.G. Greenbaum ,
Y.S. Pak ,
K.J. Adamic ,
M.C. Wintersgill  and
J.J. Fontanella
S.G. Greenbaum
Affiliation:
Hunter College of CUNY, Department of Physics, New York, NY 10021 Weizmann Institute of Science, Department of Chemical Physics, Rehovot, Israel
Y.S. Pak
Affiliation:
Hunter College of CUNY, Department of Physics, New York, NY 10021
K.J. Adamic
Affiliation:
Hunter College of CUNY, Department of Physics, New York, NY 10021
M.C. Wintersgill
Affiliation:
U.S. Naval Academy, Department of Physics, Annapolis, MD 21402
J.J. Fontanella
Affiliation:
U.S. Naval Academy, Department of Physics, Annapolis, MD 21402
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Abstract

The results of several investigations of solvent-free polymer electrolytes by nuclear magnetic resonance (NMR) spectroscopy conducted by the authors and other groups are reviewed. 23Na NMR spectra of a wide variety of amorphous polymer electrolytes are characteristic of the second-order quadrupole broadened central ± 1/2 transition with a distribution of quadrupole couplings. The temperature dependence of the linewidth is similar across a wide range of materials, and highlights the importance of polymer segmental motions above the glass transition temperature to ion mobility. Strong cation-anion interactions in poly(propylene oxide) complexes are indicated by measurements of mobile ion concentrations and, in some cases, the observation of salt precipitation at elevated temperature.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 210: Symposium L – Solid State Ionics II , 1990 , 237
Copyright
Copyright © Materials Research Society 1991

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