Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-27T01:43:40.273Z Has data issue: false hasContentIssue false
  • English
  • Français

New Perovskite Oxide (Tl1/2Na1/2)TiO3

Published online by Cambridge University Press:  16 February 2011

Yue Jin Shan ,
Tetsuro Nakamura ,
Mayuko Miyata ,
Kazuhisa Kobashi ,
Yoshiyuki Inaguma  and
Mitsuru Itoh
Yue Jin Shan
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya 321-8585, Japan
Tetsuro Nakamura
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya 321-8585, Japan
Mayuko Miyata
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya 321-8585, Japan
Kazuhisa Kobashi
Affiliation:
Materials and Structure Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, JapanE-mail: [email protected]
Yoshiyuki Inaguma
Affiliation:
Materials and Structure Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, JapanE-mail: [email protected]
Mitsuru Itoh
Affiliation:
Materials and Structure Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, JapanE-mail: [email protected]
Get access

Abstract

New perovskite-type oxide (Tl1/2Na1/2)TiO3 was synthesized by a cubic-anvil-type high pressure apparatus at 5.5 GPa and 1273 K for 30 sec. The perovskite-phase was found to have a tetragonal symmetry with space group P4/mmm. The lattice parameters a and c are 0.3811 nm and 0.3826 nm, respectively. An insulating skin covered the sample, but real resistivity is smaller and shows a metallic behavior.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 547: Symposium DD – Solid-State Chemistry of Inorganic Materials II , 1998 , 105
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Inaguma, Y., Shon, J.H., Kim, I.S., Itoh, M. and Nakamura, T., J. Phys. Soc. Jpn., 61, p. 3831 (1992).Google Scholar
[2] Sun, P.H., Nakamura, T., Shan, Y.J., Inaguma, Y. and Itoh, M., Ferroelectrics, 200, p. 93 (1997).Google Scholar
[3] Shan, Y.J., Nakamurra, T., Inaguma, Y. and Itoh, M., Solid State lonics., 108, p. 123 (1998).Google Scholar
[4] Kim, Y.-I. and lzumi, F., J. Ceram. Soc. Jpn., 102, p. 401 (1994).Google Scholar
[5] Hoppe, R. and Werding, G., Z.anorg.allg. Chem., 307, p. 174 (1961).Google Scholar
[6] Hoppe, R. and Rohrborn, H.J., Z.anorg.allg. Chem., 327, p. 199 (1964).Google Scholar