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Nanopore Organic-Inorganic Hybrid Materials with Properties of Cell Regeneration: Physicochemical and Morphological Characterization

Published online by Cambridge University Press:  28 November 2012

M. A. Hernandez ,
F. Rojas ,
F. Hernández  and
M. A. Salgado
M. A. Hernandez
Affiliation:
Departamento de Investigación en Zeolitas, Instituto de Ciencias de la Universidad Autónoma de Puebla, Edif. 103-O, Complejo de Ciencias, Puebla 72570, México.
F. Rojas
Affiliation:
Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, México. P.O. Box 55-534, México, 09340, D.F., México.
F. Hernández
Affiliation:
Departamento de Investigación en Zeolitas, Instituto de Ciencias de la Universidad Autónoma de Puebla, Edif. 103-O, Complejo de Ciencias, Puebla 72570, México.
M. A. Salgado
Affiliation:
Facultad de Ciencias Químicas, Universidad Autónoma de Puebla, 14 sur y Av. San Claudio, San Manuel, C.U., CP 72570, Puebla, México
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Abstract

Organic nanoparticles were deposited on LTA, ZSM5, FAU, clinoptilolite zeolites and montmorillonite clay forming a group of hybrid materials. The nanoparticles were analyzed by GC-Mass and proceed from the active phase of a plant constituted by 1.2 benzenedicarboxylic acid (66.1%), mono (2 ethilester) (66.1%), hexadecanoic acid (74.9%), and Y-isosterol (81.4%). Each of the hybrid materials was characterized by XRD, SEM and EDS. Additionally; the materials obtained were analyzed by high resolution adsorption (HRAD). The N2adsorption isotherms at 76 K obtained in the presence or absence of nanoparticles showed an Ia character for (LTA, FAU and ZSM5) synthetic zeolites, whilst (clinoptilolite) natural zeolite and clay (montmorillonite) showed a type II-IV character. The adsorption capacity of these substrates was analyzed by means of the Lagnmuir, de Boer, and Gursvitch rule approachs. The supermicropores present were measured by the NLDFT approach. The results indicated that the growth of nanoparticles in zeolites resulted in the emergence and opening of emerging pores of different geometry. However, in the case of ZSM5 and LTA zeolites their porosities were blocked by the nanoparticles.

Keywords

BiologicalOrganicChemical composition
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1487: Symposium S4B – Biomaterials for Medical Applications-2012 , 2012 , imrc12-s4b-p041
Copyright
Copyright © Materials Research Society 2012 

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References

REFERENCES

Spange, S., Gräser, A., Chem. Mater. 13, 3698 (2001).CrossRefGoogle Scholar
Corma, A., Díaz, U., García, T., Sastre, G., J. Am. Chem. Soc., 15011, 132 (2010).Google Scholar
Suliman, A., Tang, Y., Xu, L., Sol. Energy Mater. Sol. Cells, 91, 1658 (2007).CrossRefGoogle Scholar
Rosabal, B., Rodríguez, G., Bogdanchikova, N., Bosch, P., Microporous and Mesoporous Materials, 86, 249 (2005).CrossRefGoogle Scholar
Susarrey, A., Petranovskii, V., Herrera, M., Hernández, M. A., Portillo, R., de la Cruz, W.. J. of Nanoscience and Nanotechnology, 11, 1 (2011).Google Scholar
Haggerty, G. M., Bowman, R. S., Environ. Sci. Technol. 28, 452 (1994).CrossRefGoogle Scholar
Collella, C. in 8th International Conference of the Occurrence, Properties, and Utilization of Natural Zeolites, Edited by Petrov, O., and Tzvetanova, Y. (INZA, Sofia, 2010) p 21.Google Scholar
Pavelic, K.,·Hadžija, M., J Mol Med 78,708 (2001).CrossRefGoogle Scholar
Pavelic, K. in 8th International Conference of the Occurrence, Properties, and Utilization of Natural Zeolites, edited by Petrov, O., and Tzvetanova, Y. (INZA, Sofia, 2010) p 28.Google Scholar
Susarrey, A., Hernández, M. A., Rojas, F., Reed, C., Petranovskii, V., Licea, A., Part. Part. Syst. Charact. 27, 1 (2010).Google Scholar
Bogdanchikova, N., Concepción, B., Petranoskii, V., Avalos, M., Rodríguez, G., Studies in Surface Science and Catalysis, 135, 243 (2001).CrossRefGoogle Scholar
Breck, D. W., Zeolite Molecular Sieves (John Willey and Sons, New York, 1974) pp. 133, 139, 373.Google Scholar
Sing, K. S. W., Everett, D. H., Haul, R. A. W., Moscou, L., Pierrotti, R. A., Rouquerol, J., Siemienieswka, T., Pure Appl. Chem. 57, 603 (1985).CrossRefGoogle Scholar
Ravikovitch, P. I., Neimark, A. V., J. Phys. Chem. B, 105, 6817 (2001).CrossRefGoogle Scholar