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Nanodiamond-based Nanolubricants: Experiment and Modeling

Published online by Cambridge University Press:  29 August 2014

D. Brenner ,
Z. Mahbooba ,
F. Saberi-Movahed ,
J. Krim ,
Z. Liu ,
M.G. Ivanov ,
E. Osawa  and
O. Shenderova
D. Brenner
Affiliation:
North Carolina State University
Z. Mahbooba
Affiliation:
North Carolina State University
F. Saberi-Movahed
Affiliation:
North Carolina State University
J. Krim
Affiliation:
North Carolina State University
Z. Liu
Affiliation:
North Carolina State University
M.G. Ivanov
Affiliation:
Ural Federal University, Yekaterinburg, Russia
E. Osawa
Affiliation:
NanoCarbon Research Institute, Tokita, Japan
O. Shenderova
Affiliation:
International Technology Center, Raleigh, NC, USA
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Abstract

Our recent efforts using primarily nanodiamonds as lubricant additives are discussed. For traditional high performance engine oils, our results show a reduction in friction for steel surfaces for both laboratory experiments under controlled conditions and in a pilot study of passenger cars under typical driving conditions. Examination of the surfaces suggests that surface polishing at the sub-micron scale may be responsible for these results. A separate set of experiments using a quartz crystal microbalance to measure dissipation and drag due to friction has shown that when added to water the charge of the nanodiamond acquired from surface functionalization can have a large influence on uptake and friction at the water-metal interface. More importantly, these results suggest the possibility of creating nanodiamonds with controllable frictional drag at the solid-liquid interface through surface processing. Companion simulation results for nanodiamonds in water sliding between diamond surfaces are also presented. Future possibilities for further understanding and tuning the properties of nanodiamonds as lubricant additives through synergistic experiments and modeling are also discussed.

Keywords

tribologyCsimulation
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1703: Symposium PP – Nanodiamonds—Fundamentals and Applications , 2014 , mrss14-1703-pp05-04
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Betton, C. L. “Lubricants and their environmental impact”, in Chemistry and technology of lubricants, 3rd edition (Mortier, R. M., et al. . editors), pp. 435–459, Springer, New York, 2010.Google Scholar
Abdelmaksoud, M., Bender, J. W., Krim, J., “Nanotribology of a vapor-phase lubricant: A quartz crystal microbalance study of tricresylphosphate (TCP) uptake on iron and chromium”, Tribology Letters 13 (3): 179–186, (2002).CrossRefGoogle Scholar
Saba, C.S. and Forster, N.H., “Reactions of aromatic phosphate esters with metals and their oxides”, Tribology Letters 12, pp135–146 (2002).CrossRefGoogle Scholar
Forster, H., “Rolling Contact Testing of Vapor Phase Lubricants (III): Surface Analysis”, Tribology Transactions 40, 1 (1999).CrossRefGoogle Scholar
Abdelmaksoud, M., Bender, J. W., and Krim, J., “Bridging the gap between macro- and nanotribology: A quartz crystal microbalance study of tricresylphosphate uptake on metal and oxide surfaces”, Physical Review Letters 92, (17): Art. # 176101, (2004).CrossRefGoogle ScholarPubMed
Hu, Z.S., Dong, J.X. “Study on anti-wear and reducing friction additive of nanometer titanium oxide” Wear 216, pp. 92–96 (1998).CrossRefGoogle Scholar
Dong, X., Hu, Z.S. “A study of the anti-wear and friction-reducing properties of the lubricant additive, nanometer zinc borate”, Tribology International 31, pp. 219–223 (1998).CrossRefGoogle Scholar
Hu, Z.S., Dong, J.X., Chen, G.X., “Study on anti-wear and reducing friction additive of nanometer ferric oxide”, Tribology International 31, pp. 355–360 (1998).CrossRefGoogle Scholar
Qiu, S., Zhou, Z., Dong, J., Chen, G., “Preparation of Ni nanoparticles and evaluation of their tribological performance as potential additives in oils”, J. Tribol. 123, pp. 441–443(2001).CrossRefGoogle Scholar
Dong, J.X., Chen, G., Qiu, S., “Wear and friction behaviour of CaCO3 nanoparticles used as additives in lubricating oils”, Lubr. Sci., 12, pp. 205–212 (2000).Google Scholar
Li, B., Wang, X., Liu, W., Xue, Q., “Tribochemistry and antiwear mechanism of organic–inorganic nanoparticles as lubricant additives”, Tribology Letters 22, pp. 79–84 (2006).CrossRefGoogle Scholar
Hernández Battez, A., González, R., Viesca, J.L., Fernández, J.E., Díaz Fernández, J.M., Machado, A., Chou, R., Riba, J., “CuO, ZrO2 and ZnO nanoparticles as antiwear additive in oil lubricants”, Wear 265, pp. 422–428 (2008)CrossRefGoogle Scholar
Chou, R., Battez, A.H., Cabello, J.J., Viesca, J.L., Osorio, A., Sagastume, A., “Tribological behavior of polyalphaolefin with the addition of nickel nanoparticles”, Tribology International 43, pp. 2327–2332 (2010).CrossRefGoogle Scholar
Ivanov, M.G., Pavlyshko, S.V., Ivanov, DM., Petrov, I, and Shenderova, O., (“Synergistic compositions of colloidal nanodiamond as lubricant-additive” JVST B, 28 pp. 869–877 (2010)Google Scholar
Ivanov, M., Ivanov, D., (2012) Nanodiamond nanoparticles as additives to lubricants, Ch.8 in Ultrananocrystalline Diamond, 2nd Edition, Eds. Shenderova, O., Gruen, D., Elsevier, UK, ISBN-9781437734652.Google Scholar
Yu, Dolmatov V.. (2010). “Detonation Nanodiamonds in Oils and Lubricants”. J. Superhard Mat, 32, pp. 14–20. (2010)Google Scholar
Liu, Y.H., Wang, X.K., Liu, P.X., Zheng, J.P., Shu, C.Y., Pan, G.S. and Luo, J.B., “Modification on the tribological properties of ceramics lubricated by water using fullerenol as a lubricating additive”, Science China Tech. Sci. 55, pp. 2656–2661 (2012).CrossRefGoogle Scholar
Gara, L. and Zou, Q., “Friction and Wear Characteristics of Water-Based ZnO and Al2O3 Nanofluids”, Tribology Transactions 55, pp. 345–350 (2012)CrossRefGoogle Scholar
Wang, , Wang, X., Loui, W. and Hao, J., “Rheological and Tribological Properties of Ionic Liquid-based Nanofluids Containing Functionalized Multi-walled Carbon Nanotubes”, J. Phys. Chem C 114, pp. 8749–8754 (2010).CrossRefGoogle Scholar
Nanodiamond – An Emerging Nano-carbon Material,” Ōsawa, E. in Soumiya, S. (Editor), ‘Handbook of Advanced Ceramics: Materials, Applications, Processing and Properties, 2nd Edition,’ Chapter 2.3, p. 89–102, Academic Press: Elsevier Inc.: Amsterdam, 2013.CrossRefGoogle Scholar
Shenderova, O., Koscheev, A., Zaripov, N., Petrov, I., Skryabin, Y., Detkiv, P., Turner, S., Van Tedeloo, G., “Surface Chemistry and Properties of Ozone-Purified Detonation Nanodiamond”, J. Phys. Chem. C 115, pp. 9827–9837 (2011).CrossRefGoogle Scholar
Krüger, A.; Ōsawa, E. et al. ., Carbon 43, pp. 1722–1730 (2005).CrossRefGoogle Scholar
Schrand, A.M., Hens, S.A.C., Shenderova, O.A., “Nanodiamond Particles: Properties and Perspectives for Bioapplications”, Critical Reviews in Solid State and Materials Sciences 34, pp. 18–74 (2009).CrossRefGoogle Scholar
Ivanov, M. G., Ivanov, D. M., Pavlyshko, S. V., Petrov, I., Vargas, A., McGuire, G., Shenderova, O., (2012) Nanodiamond-Based Nanolubricants, Fullerenes, Nanotubes, and Carbon Nanostructures, 20, pp. 606–610.CrossRefGoogle Scholar
Krim, J. and Widom, A., “Damping of a Crystal Oscillator by an Adsorbed Monolayer and its Relation to Interfacial Viscosity”, Physical Review B 38, pp. 12184–12189, (1988)CrossRefGoogle ScholarPubMed
Krim, J., Solina, D. and Chiarello, R., “Nanotribology of a Kr Monolayer: A Quartz Crystal Microbalance Study of Atomic-Scale Friction”, Physical Review Letters 66, pp. 181–184, (1991)CrossRefGoogle ScholarPubMed
Hussain, Y., Krim, J., and Grant, C., “OTS adsorption: A dynamic QCM study”, Colloids And Surfaces A-Physicochemical And Engineering Aspects 262, (1-3): pp. 81–86, (2005)Google Scholar
Rodahl, M., Höök, F., Krozer, A., Brzezinski, P. and Kasemo, B., “Quartz crystal microbalance setup for frequency and Q-factor measurements in gaseous and liquid environments”, Rev. Sci Instrum. 66 pp. 3924–3930 (1995).CrossRefGoogle Scholar
Rodahl, M. and Kasemo, B., “A Simple Setup to Simultaneously Measure the Resonant Frequency and Absolute Dissipation Factor of a Quartz Crystal Microbalance”, Rev. Sci. Instruments, 67, pp. 3238–3241 (1996).CrossRefGoogle Scholar
Granick, S., Zhu, Y.X. and Lee, H., “Slippery questions about complex fluids flowing past solids”, Nature Materials 2, pp.221–227 (2003)CrossRefGoogle ScholarPubMed
Borovsky, B., Krim, J., Asif, Syed, S. A., Wahl, K. J., “Measuring nanomechanical properties of a dynamic contact using an indenter probe and quartz crystal microbalance”, Journal Of Applied Physics 90 (12): pp. 6391–6396, (2001)CrossRefGoogle Scholar
Flanigan, C.M., Desai, M., Shull, K.R., “Contact Mechanics Studies with the Quartz Crystal Microbalance.” Langmuir 16 (25), pp. 9825–9829 (2000).CrossRefGoogle Scholar
Vittorias, E., Kappl, M., Butt, H.-J., Johannsmann, D., “Studying mechanical microcontacts of fine particles with the quartz crystal microbalance” Powder Technology 203 (3), pp. 489–502 (2010)CrossRefGoogle Scholar
Dawson, B.D., Lee, S.M., Krim, J., “Tribo-Induced Melting Transition at a Sliding Asperity Contact”. Phys. Rev. Lett. 103 (20), pp. 205502–205502 (2009).CrossRefGoogle Scholar
Liu, Z., Corley, S.D., Leininger, D., Shenderova, O., Brenner, D. and Krim, J., “Nanotribological Properties of positively and negatively charged nanodiamonds as additives to solutions”, Royal Society of Chemistry Advances, submitted (2014).Google Scholar
Huzayyin, A., Chang, J.H., Lian, K., Dawson, F., “Interaction of water molecule with Au(111) and Au(110) surfaces under the influence of an external electric field”, J. Phys. Chem. C 118, pp. 3459–3470 (2014).CrossRefGoogle Scholar
Coffey, T., Abdelmaksoud, M., Krim, J., “A scanning probe and quartz crystal microbalance study of the impact of C-60 on friction at solid-liquid interfaces”, Journal Of Physics-Condensed Matter 13, pp. 4991–4999, (2001).CrossRefGoogle Scholar
Haynes, W.M., “Handbook of chemistry and physics”, CRC, 94th edition, (2013-2014).Google Scholar
Kedzierski, M.A., “Viscosity and density of CuO nanolubricant”, International Journal of Refrigeration 35, pp. 1997–2002 (2012).CrossRefGoogle Scholar